Method for producing PbTiO3-containing single crystal

A single crystal production method for producing a single crystal containing PbTiO3 by a vertical Bridgman method while heating and melting a raw material to obtain a melt and supplying the melt, comprising:

• supplying an initial raw material in solid form to a cone part of a crucible and an adjacent region above said cone part,
• heating and melting the initial raw material in the crucible to form a melt layer on an upper side of a seed crystal, wherein said melt layer has a predetermined thickness of at least 30 mm in said adjacent region above said cone part,
• lowering the crucible in an environment having a temperature gradient in which the temperature at a lower section becomes lower,
• starting unidirectional solidification of said melt layer from a part coming into contact with the seed crystal,
• solidifying said melt layer up to an upper end face of the cone part,
• dropping the additional melt obtained by heating and melting a raw material in a sub-crucible into the crucible,
• lowering the crucible while maintaining said predetermined thickness of said melt layer in said adjacent region above said cone part by balancing and adjusting the speed of lowering the crucible and supply rate by dropping of the additional melt, and
• producing the single crystal.