Use of tetrahydrobenzoxazines as stabilizers
AssigneeBASF SE
InventorsArno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
Life of this patent
Estimating the term…
Abstract
The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.
Claims15
An antioxidant for stabilizing mineral oil products and fuels against the action of light, oxygen and heat, comprising:
- a tetrahydrobenzoxazine of formula I:
- wherein R1 is a 2-aminoethyl-, a N-(2′-aminoethyl-)-2-aminoethyl-, a N′-(2″-aminoethyl-)-N-(2′-aminoethyl-)-2-aminoethyl-, a N″-(2′″-aminoethyl-)-N′-(2″-aminoethyl-)-N-(2′-aminoethyl-)-2-aminoethyl-, or a 3-dimethylaminopropyl-radical,
- and
- R2, R3, R4 and R5 are each independently a hydrogen atom, a hydroxyl group or a hydrocarbyl radical having from 1 to 3000 carbon atoms which may optionally be interrupted by one or more selected from the group consisting of O, S and NR6 moieties,
- wherein R4 may optionally be a radical of formula Y
- wherein R1, R2, R3 and R5 are each as defined above and X is a hydrocarbon bridging element which consists of one or more isobutene units or comprises one or more isobutene units, or wherein R4 may optionally be a radical of the formula Z or Z′
- wherein R1, R2, R3 and R5 are each as defined above and R10 and R11 are each independently hydrogen or a C1- to C10-alkyl radical,
- and wherein R2 and R3 or R3 and R4 or R4 and R5, together with the part-structure —O—CH2—NR7—CH2— attached to the benzene ring, may optionally form a second tetrahydrooxazine ring, or R2 and R3 and R4 and R5, together with the part-structures —O—CH2—NR7—CH2— and —O—CH2—NR8—CH2— attached to the benzene ring, may optionally form a second and a third tetrahydrooxazine ring,
- wherein R7 and R8 are each independently a hydrocarbyl radical having from 1 to 3000 carbon atoms and are interrupted by one or more heteroatoms selected from the group consisting of O, S and NR6 moieties, with the proviso that at least one of R2, R3, R4, or R5 is a polyisobutenyl radical having a number-average molecular weight Mn of from 200 to 40,000.
Dependencies are inferred from the claim text.