Injectable tissue supplement

An aqueous solution comprising a polymer dissolved therein, wherein the polymer in the aqueous solution comprises:

• (a) one or more monomers selected from compounds of Formulas I and II;
• and (b) one or more monomers selected from compounds of Formula XXXV, wherein compounds of Formulas I and II are:
• wherein:
• R1, R2, R4, R5, R6, R7, R11, R12, R13, and R14 are each independently selected from the group consisting of alkyl, alkenyl, alkynyl, H, halide, ether-linked alkyl, ether-linked alkenyl, ether-linked alkynyl;
• R8, R9 and R10 are independently alkyl;
• R3 is selected from the group consisting of hydrogen, a straight or branched alkyl, cycloalkyl, aryl, olefin, silyl, alkylsilyl, arylsilyl, alkylaryl, arylalkyl, methoxy, ethoxy, amino, or fluorocarbon chain of 1-50 carbons, wherein each alkyl, cycloalkyl, aryl, olefin, silyl, alkylsilyl, arylsilyl, alkylaryl, arylalkyl, or fluorocarbon chain is optionally substituted internally or terminally by one or more hydroxyl, hydroxyether, carboxyl, carboxyester, carboxyamide, amino, mono- or di-substituted amino, thiol, thioester, sulfate, phosphate, phosphonate, or halogen substituents;
• X is O;
• Q1, Q2 and Q3 are each C;
• E1, E2, E3, E4, E5 are each O;
• n and m can each independently range from 0-14;
• and
• m is 1-14;
• compounds of Formulas XXXV are:
• wherein:
• R1, R2, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, and R14 are each independently selected from the group consisting of alkyl, alkenyl, alkynyl, H, halide, ether-linked alkyl, ether-linked alkenyl, ether-linked alkynyl;
• R3 is selected from the group consisting of hydrogen, a straight or branched alkyl, cycloalkyl, aryl, olefin, silyl, alkylsilyl, arylsilyl, alkylaryl, arylalkyl, methoxy, ethoxy, amino, or fluorocarbon chain of 1-50 carbons, wherein each alkyl, cycloalkyl, aryl, olefin, silyl, alkylsilyl, arylsilyl, alkylaryl, arylalkyl, or fluorocarbon chain is optionally substituted internally or terminally by one or more hydroxyl, hydroxyether, carboxyl, carboxyester, carboxyamide, amino, mono- or di-substituted amino, thiol, thioester, sulfate, phosphate, phosphonate, or halogen substituents;
• Q1, Q2, Q3 and Q4 are each C;
• E1 and E2 are each O;
• and
• a is an integer from 0-1200.