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US 9,752,218 B2Granted
Zirconium-based and beryllium free bulk amorphous alloy
AssigneeThe Swatch Group Research and Development Ltd
InventorsAlban Dubach, Yves Winkler, Tommy Carozzani
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Abstract
The invention concerns a zirconium and/or hafnium based, beryllium free, bulk, amorphous alloy, with the addition of silver and/or gold and/or platinum to increase its critical diameter.
Claims20
A beryllium-free bulk amorphous alloy, consisting of:
- in atomic percentage,
- 50%-63% of zirconium and/or hafnium as a base;
- 1.5%-4.5% of at least one first additional metal selected from the group consisting of titanium, niobium, and tantalum, wherein niobium is less than or equal to 2.5%;
- 0.5%-4.5% of at least one second additional metal selected from the group consisting of silver, gold, and platinum;
- 8.5%-17.5% of at least one third additional metal selected from the group consisting of nickel, cobalt, manganese, and iron;
- 9%-13% of aluminum;
- 10%-17.9% of copper;
- and
- inevitable impurities,
- wherein the alloy has ΔTx as calculated below of 98 K or less:
- ΔTx=Tx−Tg, where Tx and Tg is a crystallization point and a glass transition point of the alloy, respectively.
8 more elements
A beryllium-free bulk amorphous alloy, consisting of:
- in atomic percentage,
- 50%-63% of zirconium and/or hafnium as a base;
- 1.5%-4.5% of at least one first additional metal selected from the group consisting of titanium, niobium, and tantalum, wherein niobium is less than or equal to 2.5%;
- 0.5%-4.5% of at least one second additional metal selected from the group consisting of silver, gold, palladium, and platinum;
- 8.5%-17.5% of at least one third additional metal selected from the group consisting of chromium, cobalt, manganese, and iron;
- 9%-13% of aluminum;
- 10%-17.9% of copper;
- and
- inevitable impurities,
- wherein the alloy has ΔTx as calculated below of 98 K or less:
- ΔTx=Tx−Tg, where Tx and Tg is a crystallization point and a glass transition point of the alloy, respectively.
8 more elements
Dependencies are inferred from the claim text.