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US 9,752,056 B2Granted
Radiation-curing, water-dispersible polyurethane (meth)acrylates
AssigneeBASF SE
InventorsSebastian Berger, Peter Thuery, Susanne Neumann, Tanja Becker, Axel Becker
Life of this patent
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Abstract
The present invention describes radiation-curable, water-dispersible polyurethane acrylates which feature good grain highlighting, their use, and the method for producing them.
Claims21
A urethane (meth)acrylate (A) comprising a reaction product of:
- (a) at least one (cyclo)aliphatic di- and/or polyisocyanate,
- (b1) at least one (cyclo)aliphatic diol having a molar mass of less than 700 g/mol,
- (b2) at least one polyesterdiol having a weight-average molar mass Mw of 700 to 2000 and optionally an acid number to DIN 53240 of not more than 20 mg KOH/g,
- (c) at least one compound (c) having at least one isocyanate-reactive group and at least one radically polymerizable unsaturated group,
- (d) at least one compound which has at least one isocyanate-reactive group and at least one acid group,
- (e) at least one base for at least partial neutralization of at least one acid group of component (d), being different from components (h1) and (h2),
- (f) optionally at least one monoalcohol, having precisely one hydroxyl function,
- (g) optionally at least one monofunctional polyalkylene oxide polyether alcohol,
- (h1) at least one monoamine which is substituted by one or two hydrocarbon radicals, in which the one or two hydrocarbon radicals together have at least 12 carbon atoms, and
- (h2) optionally at least one compound having at least two primary and/or secondary amino groups,
- wherein the urethane (meth)acrylate (A) is obtained by a process comprising reacting at least a portion of components (b1), (b2), and (c) with component (a).
8 more elements
Dependencies are inferred from the claim text.