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US 9,752,002 B2Granted
Fiber-reinforced thermoplastic resin prepreg, molded body of same, and method for producing fiber-reinforced thermoplastic resin prepreg
AssigneeMitsubishi Chemical Corporation
InventorsSaki Fujita, Tadashi Ohtani, Atsushi Takahashi, Kiyotoshi Fujioka
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Abstract
A fiber-reinforced thermoplastic resin prepreg containing (A) reinforcing fibers, (B) a sizing agent and (C) a polyamide resin is described, wherein the sizing agent (B) and the polyamide resin (C) satisfy the condition Nm/N0<4.0, wherein N0 is the average of torques necessary for maintaining the number of revolutions of a roller type blade at 100 rpm/15 minutes.
Claims6
A method for producing a fiber-reinforced thermoplastic resin prepreg, the method comprising adding (C) a polyamide resin in a melted state to a plurality of (A) reinforcing fibers adhering to (B) a sizing agent and pressurizing at a temperature that is higher than a melting point of (C) the polyamide resin by 10 to 60° C. and at a pressure of 0.1 to 5.0 MPa, wherein
- (A) the reinforcing fibers have a weight per unit area (g/m2) of 50 to 300,
- (C) the polyamide resin is at least one resin selected from the group consisting of Nylon 6, Nylon 12, Nylon 610, Nylon 612 and Nylon MXD6, where the polyamide resin has a melting point of 250° C. or lower, and
- in which (B) the sizing agent and (C) the polyamide resin satisfy the following conditions:
- Nm/N0≦2
- wherein N0 is an average of torques of a roller type blade required for maintaining number of revolutions of a roller type blade at 100 rpm for 15 minutes, an average representing the fluidity of (C) the polyamide resin in cases where a mixer having a volume of 60 cc and a roller type blade is used, only (C) the polyamide resin is filled into the mixer such that filling ratio is 60% relative to the volume of the mixer, and the resin is heated and melted at a temperature that is higher than the melting point of (C) the polyamide resin by 30° C.;
- and
- wherein Nm, is an average of torques of a roller type blade required for maintaining a number of revolutions of a roller type blade at 100 rpm for 15 minutes, the average representing the fluidity of a mixture which is obtained by using a mixer having a volume of 60 cc and a roller type blade, filling the mixer with a mixture, in which (B) the sizing agent and (C) the polyamide resin are mixed at 3:100 (mass ratio), such that the filling ratio is 60% relative to the volume of the mixer, and heating and melting the mixture at a temperature that is higher than the melting point of (C) the polyamide resin by 30° C.
4 more elements
A fiber-reinforced thermoplastic resin prepreg comprising (A) reinforcing fibers, (B) a sizing agent, and (C) polyamide resin, wherein
- (A) the reinforcing fibers have a weight per unit area (g/m2) of 50 to 300,
- (C) the polyamide resin is at least one resin selected from the group consisting of Nylon 6, Nylon 12, Nylon 610, Nylon 612 and Nylon MXD6, where the polyamide resin has a melting point of 250° C. or lower, and
- (B) the sizing agent and (C) the polyamide resin satisfy the following conditions:
- Nm/N0≦2
- wherein N0 is an average of torques of a roller type blade required for maintaining the number of revolutions of a roller type blade at 100 rpm for 15 minutes, the average representing the fluidity of (C) the polyamide resin in cases where a mixer having a volume of 60 cc and a roller type blade is used, only (C) the polyamide resin is filled into the mixer such that the filling ratio is 60% relative to the volume of the mixer, and the resin is heated and melted at a temperature that is higher than the melting point of (C) the polyamide resin by 30° C.,
- wherein Nm is an average of torques of a roller type blade required for maintaining the number of revolutions of a roller type blade at 100 rpm for 15 minutes, the average representing the fluidity of a mixture, which is obtained by using a mixer having a volume of 60 cc and a roller type blade, filling the mixer with a mixture in which (B) the sizing agent and (C) the polyamide resin are mixed at 3:100 (mass ratio), such that the filling ratio is 60% relative to the volume of the mixer, and heating and melting the mixture at a temperature that is higher than the melting point of (C) the polyamide resin by 30° C., and
- wherein a complex viscosity of (C) the polyamide resin is 30 to 250 Pa-s under the following measurement conditions:
- <Measurement conditions>
- The complex viscosity measured at a temperature that is higher than the melting point of (C) the polyamide resin by 30° C., an angular frequency of 0.1 rad/s, and a displacement of 20% by dynamic viscoelasticity measurement using a rotary viscometer, in which a parallel plate is used, is defined as melt viscosity.
6 more elements
A fiber-reinforced thermoplastic resin prepreg comprising (A) reinforcing fibers, (B) a sizing agent, and (C) polyamide resin, wherein
- (A) the reinforcing fibers have a weight per unit area (g/m2) of 50 to 300,
- (C) the polyamide resin is at least one resin selected from the group consisting of Nylon 6, Nylon 12, Nylon 610, Nylon 612 and Nylon MXD6, where the polyamide resin has a melting point of 250° C. or lower, and
- (B) the sizing agent and (C) the polyamide resin satisfy the following conditions:
- Nm/N0≦2
- wherein N0 is an average of torques of a roller type blade required for maintaining the number of revolutions of a roller type blade at 100 rpm for 15 minutes, the average representing the fluidity of (C) the polyamide resin in cases where a mixer having a volume of 60 cc and a roller type blade is used, only (C) the polyamide resin is filled into the mixer such that the filling ratio is 60% relative to the volume of the mixer, and the resin is heated and melted at a temperature that is higher than the melting point of (C) the polyamide resin by 30° C.,
- wherein Nm, is an average of torques of a roller type blade required for maintaining the number of revolutions of a roller type blade at 100 rpm for 15 minutes, the average representing the fluidity of a mixture, which is obtained by using a mixer having a volume of 60 cc and a roller type blade, filling the mixer with a mixture in which (B) the sizing agent and (C) the polyamide resin are mixed at 3:100 (mass ratio), such that the filling ratio is 60% relative to the volume of the mixer, and heating and melting the mixture at a temperature that is higher than the melting point of (C) the polyamide resin by 30° C., and
- wherein (B) the sizing agent contains at least one compound selected from the group consisting of a compound (A1) which is represented by the following formula (1) and a compound (B1) which is represented by the following formula (2)
- where for Formula (1), R1 and R2 are each independently a hydrogen atom or an alkyl group, R1 and R2 being the same or different from each other;
- and j and k are each independently an integer of 1 or higher, provided that the sum of j and k is an integer of 14 to 40;
- where for Formula (2), R3 and R4 are each independently a hydrogen atom or an alkyl group, R3 and R4 being the same or different from each other;
- and m and n are each independently an integer of 1 or higher, provided that the sum of m and n is an integer of 54 to 100,
- wherein (B) the sizing agent comprises a mixture of the compound (A1) and the compound (B1) and the mass ratio (A1)/(B1) is within a range of from 2/1 to 1/2.
9 more elements
A fiber-reinforced thermoplastic resin prepreg comprising (A) reinforcing fibers, (B) a sizing agent, and (C) polyamide resin, wherein
- (A) the reinforcing fibers have a weight per unit area (g/m2) of 50 to 300,
- (C) the polyamide resin is at least one resin selected from the group consisting of Nylon 6, Nylon 12, Nylon 610, Nylon 612 and Nylon MXD6, where the polyamide resin has a melting point of 250° C. or lower, and
- (B) the sizing agent and (C) the polyamide resin satisfy the following conditions:
- Nm/N0≦2
- wherein N0 is an average of torques of a roller type blade required for maintaining the number of revolutions of a roller type blade at 100 rpm for 15 minutes, the average representing the fluidity of (C) the polyamide resin in cases where a mixer having a volume of 60 cc and a roller type blade is used, only (C) the polyamide resin is filled into the mixer such that the filling ratio is 60% relative to the volume of the mixer, and the resin is heated and melted at a temperature that is higher than the melting point of (C) the polyamide resin by 30° C.,
- wherein Nm is an average of torques of a roller type blade required for maintaining the number of revolutions of a roller type blade at 100 rpm for 15 minutes, the average representing the fluidity of a mixture, which is obtained by using a mixer having a volume of 60 cc and a roller type blade, filling the mixer with a mixture in which (B) the sizing agent and (C) the polyamide resin are mixed at 3:100 (mass ratio), such that the filling ratio is 60% relative to the volume of the mixer, and heating and melting the mixture at a temperature that is higher than the melting point of (C) the polyamide resin by 30° C., and
- wherein (B) the sizing agent is a sizing agent containing:
- a compound (A) which is an ester formed by reaction between an epoxy compound having one or more and three or less epoxy groups in the molecule and an unsaturated monobasic acid and having at least one epoxy group in the molecule;
- a urethane acrylate oligomer (B) of a bifunctional type;
- and
- an ester compound (C) which is an ester formed by reaction between an alkylene oxide adduct of bisphenols and a dicarboxylic acid compound and having an acid number of 50 or higher,
- the mass ratio of the content of the urethane acrylate oligomer (B) to the compound (A) being within a range of 1/3 to 2/1, and
- the content of the ester compound (C) being not more than 2.0 fold by mass greater than the total amount of the compound (A) and the urethane acrylate oligomer (B).
10 more elements
A fiber-reinforced thermoplastic resin prepreg comprising (A) reinforcing fibers, (B) a sizing agent, and (C) polyamide resin, wherein
- (A) the reinforcing fibers have a weight per unit area (g/m2) of 50 to 300,
- (C) the polyamide resin is at least one resin selected from the group consisting of Nylon 6, Nylon 12, Nylon 610, Nylon 612 and Nylon MXD6, where the polyamide resin has a melting point of 250° C. or lower, and
- (B) the sizing agent and (C) the polyamide resin satisfy the following conditions:
- Nm/N0≦2
- wherein N0 is an average of torques of a roller type blade required for maintaining the number of revolutions of a roller type blade at 100 rpm for 15 minutes, the average representing the fluidity of (C) the polyamide resin in cases where a mixer having a volume of 60 cc and a roller type blade is used, only (C) the polyamide resin is filled into the mixer such that the filling ratio is 60% relative to the volume of the mixer, and the resin is heated and melted at a temperature that is higher than the melting point of (C) the polyamide resin by 30° C.,
- wherein Nm, is an average of torques of a roller type blade required for maintaining the number of revolutions of a roller type blade at 100 rpm for 15 minutes, the average representing the fluidity of a mixture, which is obtained by using a mixer having a volume of 60 cc and a roller type blade, filling the mixer with a mixture in which (B) the sizing agent and (C) the polyamide resin are mixed at 3:100 (mass ratio), such that the filling ratio is 60% relative to the volume of the mixer, and heating and melting the mixture at a temperature that is higher than the melting point of (C) the polyamide resin by 30° C., and
- wherein the N0 is 2.08 or lower.
4 more elements
Dependencies are inferred from the claim text.