US 9,751,960 B2 · Catalyst component for olefin polymerization, catalyst, and use thereof

Abstract

The present disclosure provides a solid catalyst component for olefin polymerization, comprising magnesium, titanium, a halogen, and an electron donor, wherein the electron donor is at least one selected from the group consisting of diol diester compounds as shown in Formula (I). The catalyst according to the present disclosure has significantly improved polymerization activity, hydrogen response, and stereoselectivity. According to the present disclosure, when the catalyst system containing a diol diester compound as shown in Formula (I) of the present disclosure is used in olefin polymerization, the catalyst shows good comprehensive performance, including high catalytic activity. In particular, in the presence of highly concentrated hydrogen, the catalyst has an improved hydrogen response and/or isotacticity of the polymers obtained can be significantly improved. The catalyst of the present disclosure is beneficial for obtaining polymers with a high melt index and high isotacticity, and for development of polymers of different grades.

A catalyst component for olefin polymerization, comprising magnesium, titanium, a halogen, and an electron donor, wherein the electron donor is at least one selected from the group consisting of diol diester compounds, wherein the diol diester compounds are one or more selected from the group consisting of 2,4-hexanediol-bis(4-ethyl benzoate),

2,4-hexanediol-bis(4-n-propyl benzoate),
2,4-hexanediol-bis(4-n-butyl benzoate),
2,4-hexanediol-bis(4-iso-butyl benzoate),
2,4-hexanediol-bis(4-tert-butyl benzoate),
2,4-hexanediol-bis(4-hexyl benzoate),
3-methyl-2,4-hexanediol-bis(4-ethyl benzoate),
3-methyl-2,4-hexanediol-bis(4-n-propyl benzoate),
3-methyl-2,4-hexanediol-bis(4-n-butyl benzoate),
3-methyl-2,4-hexanediol-bis(4-iso-butyl benzoate),
3-methyl-2,4-hexanediol-bis(4-tert-butyl benzoate),
3-methyl-2,4-hexanediol-bis(4-hexyl benzoate),
3-ethyl-2,4-hexanediol-bis(4-ethyl benzoate),
3-ethyl-2,4-hexanediol-bis(4-n-propyl benzoate),
3-ethyl-2,4-hexanediol-bis(4-n-butyl benzoate),
3-ethyl-2,4-hexanediol-bis(4-iso-butyl benzoate),
3-ethyl-2,4-hexanediol-bis(4-tert-butyl benzoate),
3-ethyl-2,4-hexanediol-bis(4-hexyl benzoate),
3,5-heptanediol-bis(4-n-propyl benzoate),
3,5-heptanediol-bis(4-iso-propyl benzoate),
3,5-heptanediol-bis(4-iso-butyl benzoate),
3,5-heptanediol-bis(4-tert-butyl benzoate),
3,5-heptanediol-bis(4-pentyl benzoate),
3,5-heptanediol-bis(4-hexyl benzoate),
3,5-heptanediol-cinnamic acid-4-ethyl benzoate,
4-methyl-3,5-heptanediol-bis(4-ethyl benzoate),
4-methyl-3,5-heptanediol-bis(4-n-propyl benzoate),
4-methyl-3,5-heptanediol-bis(4-iso-propyl benzoate),
4-methyl-3,5-heptanediol-bis(4-n-butyl benzoate),
4-methyl-3,5-heptanediol-bis(4-iso-butyl benzoate),
4-methyl-3,5-heptanediol-bis(4-tert-butyl benzoate),
4-methyl-3,5-heptanediol-bis(4-pentyl benzoate),
4-methyl-3,5-heptanediol-bis(4-hexyl benzoate),
4-methyl-3,5-heptanediol-cinnamic acid-4-ethyl benzoate,
4-ethyl-3,5-heptanediol-bis(4-ethyl benzoate),
4-ethyl-3,5-heptanediol-bis(4-n-propyl benzoate),
4-ethyl-3,5-heptanediol-bis(4-iso-propyl benzoate),
4-ethyl-3,5-heptanediol-bis(4-n-butyl benzoate),
4-ethyl-3,5-heptanediol-bis(4-iso-butyl benzoate),
4-ethyl-3,5-heptanediol-bis(4-tert-butyl benzoate),
4-ethyl-3,5-heptanediol-bis(4-pentyl benzoate),
4-ethyl-3,5-heptanediol-bis(4-hexyl benzoate),
4-ethyl-3,5-heptanediol-cinnamic acid-4-ethyl benzoate,
4-n-propyl-3,5-heptanediol-bis(4-tert-butyl benzoate),
4-n-butyl-3,5-heptanediol-bis(4-tert-butyl benzoate),
4,4-dimethyl-3,5-heptanediol-bis(4-tert-butyl benzoate),
4-methyl-4-ethyl-3,5-heptanediol-bis(4-tert-butyl benzoate),
4-methyl-4-n-propyl-3,5-heptanediol-bis(4-tert-butyl benzoate),
3-methyl-2,4-heptanediol-bis(4-n-propyl benzoate),
3-methyl-2,4-heptanediol-bis(4-iso-propyl benzoate),
4-methyl-3,5-octanediol-bis(4-tert-butyl benzoate),
4-ethyl-3,5-octanediol-bis(4-tert-butyl benzoate),
4-n-propyl-3,5-octanediol-bis(4-tert-butyl benzoate),
4-n-butyl-3,5-octanediol-bis(4-tert-butyl benzoate),
4,4-dimethyl-3,5-octanediol-bis(4-tert-butyl benzoate),
4,4-diethyl-3,5-octanediol-bis(4-n-propyl benzoate),
4,4-di-n-propyl-3,5-octanediol-bis(4-tert-butyl benzoate),
4-methyl-4-ethyl-3,5-octanediol-bis(4-tert-butyl benzoate),
4,6-nonanediol-bis(4-ethyl benzoate),
4,6-nonanediol-bis(4-n-propyl benzoate),
4,6-nonanediol-bis(4-n-butyl benzoate),
4,6-nonanediol-bis(4-iso-butyl benzoate),
4,6-nonanediol-bis(4-tert-butyl benzoate),
4,6-nonanediol-bis(4-hexyl benzoate),
4,6-nonanediol-cinnamic acid-4-ethyl benzoate,
5-methyl-4,6-nonanediol-bis(4-ethyl benzoate),
5-methyl-4,6-nonanediol-bis(4-n-propyl benzoate),
5-methyl-4,6-nonanediol-bis(4-n-butyl benzoate),
5-methyl-4,6-nonanediol-bis(4-iso-butyl benzoate),
5-methyl-4,6-nonanediol-bis(4-tert-butyl benzoate),
5-methyl-4,6-nonanediol-bis(4-hexyl benzoate),
5-ethyl-4,6-nonanediol-bis(4-ethyl benzoate),
5-ethyl-4,6-nonanediol-bis(4-n-propyl benzoate),
5-ethyl-4,6-nonanediol-bis(4-n-butyl benzoate),
5-ethyl-4,6-nonanediol-bis(4-iso-butyl benzoate),
5-ethyl-4,6-nonanediol-bis(4-tert-butyl benzoate),
5-ethyl-4,6-nonanediol-bis(4-hexyl benzoate),
5-n-propyl-4,6-nonanediol-bis(4-tert-butyl benzoate),
5-n-butyl-4,6-nonanediol-bis(4-n-butyl benzoate),
5,5-dimethyl-4,6-nonanediol-bis(4-tert-butyl benzoate),
5,5-diethyl-4,6-nonanediol-bis(4-hexyl benzoate),
5,5-di-n-propyl-4,6-nonanediol-bis(4-pentyl benzoate), and
5,5-dibutyl-4,6-nonanediol-bis(4-tert-butyl benzoate).

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Catalyst component for olefin polymerization, catalyst, and use thereof

Life of this patent

Catalyst component for olefin polymerization, catalyst, and use thereof

Life of this patent

Abstract

Claims20