A process for the preparation of an organic titanium derivative, comprising the following steps:
- (i) mixing an organic and/or inorganic compound of titanium (IV) and a 1,3-diol of formula [1]:
- wherein R1, R2, R3 and R4 are independently selected from H and a linear or branched C1-C6 alkyl radical,
- in a Ti:diol molar ratio of between 1:0.85 and 1:1.20, in the presence of at least an organic solvent immiscible with water and subsequent removal of reaction by-products;
- (ii) adding water to the reaction mixture in a H2O:Ti≧2 molar ratio and subsequent removal of unreacted water and reaction by-products;
- (iii) maturing the reaction mixture at a temperature of 180-200° C. for 16-50 hours.