Process for the production of a gasoline with a low sulfur content
AssigneeIfp Energies Nouvelles
InventorsOlivier Touzalin, Philibert Leflaive, Diamantis Asteris, Delphine Largeteau, Jean Luc Nocca
Life of this patent
Estimating the term…
Abstract
This invention relates to a process for treatment of a gasoline that comprises diolefins, olefins and sulfur-containing compounds including mercaptans, consisting of a stage for treatment of the gasoline in a distillation column (2) comprising at least one reaction zone (3) including at least one catalyst that makes it possible to carry out the addition of mercaptans to the olefins that are contained in the gasoline that distills toward the top of the catalytic column.
Claims11
A process for treating a gasoline comprising diolefins, olefins, and sulfur-containing compounds including mercaptans, consisting of a stage for treating gasoline in the presence of hydrogen in a distillation column (2) comprising at least one reaction zone (3) including at least one catalyst, with the catalyst being in sulfide form and comprising a substrate that consists of gamma-alumina or delta-alumina with a specific surface area of between 70 m2/g and 350 m2/g, a content by weight of oxide of the element of group VIb of between 1 and 30% by weight relative to the total weight of the catalyst, a content by weight of oxide of the element of group VIII of between 1 and 30% by weight relative to the total weight of the catalyst, a sulfurization rate of the metals that constitute said catalyst that is at least equal to 60%, a molar ratio between the metal of group VIII and the metal of group VIb of between 0.6 and 3 mol/mol, in which:
- gasoline is injected into the distillation column at a level located below the reaction zone (3) in such a way as to separate a desulfurized light gasoline at a point located above the reaction zone and a heavy gasoline comprising the majority of the sulfur-containing compounds at the bottom of the column, and
- concurrently the gasoline that distills at the top of the catalytic column is brought into contact with the catalyst of the reaction zone (3) and the hydrogen in such a way as to provide desulfurized light gasoline, and
- in which the distillation column is configured for operating as a depentanizer in such a way as to provide a light gasoline that has at most 5 carbon atoms or
- in which the distillation column is configured for operating as a dehexanizer in such a way as to provide a light gasoline that has at most 6 carbon atoms.
Dependencies are inferred from the claim text.