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US 9,518,211 B2Granted
Method for recovering oil
AssigneesBASF SE, Wintershall Holding GmbH
InventorsRiichiro Kimura, Stefan Maurer, Andrei-Nicolae Parvulescu, Lorenz Siggel, Ulrich Müller, Thomas Frechen, Bernd Hinrichsen
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Abstract
The present invention relates to a process for recovering oil from a subterranean formation by injecting both solid particles and water into the formation. An oil-in-water emulsion that is stabilized by solid particles is formed in the pores of the formation. This emulsion is recovered from the subterranean formation.
Claims13
A process for recovering oil from a subterranean oil-containing formation comprising at least the steps of:
- a) introducing solid particles and water into the subterranean oil-containing formation to obtain a solid particles-stabilized emulsion containing droplets, whereby water is the continuous phase and oil is the dispersed phase, and
- b) recovering said solid particles-stabilized emulsion from the subterranean oil-containing formation,
- wherein the solid particles comprise at least one layered double hydroxide of general formula (I)
- [MII(1-x)MIIIx(OH)2]x+[An−]x/n.yH2O (I),
- wherein
- MII denotes a divalent metal ion or 2Li,
- MIII denotes a trivalent metal ion,
- An− denotes an n-valent anion,
- n is 1 or 2,
- x is the mole fraction having a value ranging from 0.1 to 0.5 and
- y is a value ranging from 0 to 5.0;
- wherein the solid-particles stabilized emulsion has a viscosity at 20° C. in the range of 5 to 30 mPa·s at a temperature of 20° C. under shear rate of 10/s.
9 more elements
Dependencies are inferred from the claim text.