Aftertreatment systems with reduced N2O generation

A system, comprising:

• an internal combustion engine having an exhaust aftertreatment system for receiving an exhaust gas produced from operation of the internal combustion engine;
• a reductant system including a reductant source;
• and
• a diesel exhaust aftertreatment system that includes at least one selective catalytic reduction (SCR) catalyst positioned downstream of a connection of the reductant source to the exhaust aftertreatment system, wherein the at least one SCR catalyst includes at least three formulations on portions of the SCR catalyst, the at least three formulations including a first formulation, a second formulation, and a third formulation, wherein the first formulation produces less N2O during NOx reduction by the SCR catalyst than the second formulation, wherein:
• the first formulation is a vanadium based catalyst formulation, the second formulation is a copper-zeolite catalyst formulation, and the third formulation is an iron-zeolite catalyst formulation, wherein the first formulation includes a low copper loading washcoat applied to at least a first portion of the SCR catalyst and the second formulation includes a high copper loading washcoat applied to at least a second portion of the SCR catalyst, wherein the first portion is upstream of the second portion.

An apparatus for reducing constituents in an exhaust gas, comprising:

• at least one selective catalytic reduction (SCR) catalyst including a first portion with a first formulation and a second portion with a second formulation, wherein the first formulation produces a lesser amount of N2O during NOx reduction of the exhaust gas than the second formulation, wherein the first portion is positioned upstream of the second portion so the first portion first receives the exhaust gas, and further comprising a third formulation on the SCR catalyst, wherein:
• the first formulation is a vanadium based catalyst formulation;
• the second formulation is a copper-zeolite catalyst formulation;
• and
• the third formulation is an iron-zeolite catalyst formulation.

An apparatus for reducing constituents in an exhaust gas, comprising:

• a selective catalytic reduction (SCR) catalyst including a top washcoat and a bottom washcoat, wherein:
• the bottom washcoat includes a high copper loading SCR catalyst formulation;
• the top washcoat includes a low copper loading SCR catalyst formulation and substantially coats the bottom washcoat;
• further comprising a third catalyst formulation on the SCR catalyst, wherein:
• the top washcoat includes a vanadium based catalyst formulation;
• the bottom washcoat is a copper-zeolite catalyst formulation;
• and
• the third catalyst formulation is an iron-zeolite catalyst formulation.

A method for treating an exhaust gas, comprising:

• exposing the exhaust gas to a selective catalytic reduction (SCR) catalyst including first catalyst formulation and a second catalyst formulation;
• wherein the first catalyst formulation produces less N2O during NOx reduction by the SCR catalyst than the second formulation, and further comprising a third catalyst formulation on the SCR catalyst, wherein:
• the first catalyst formulation is a vanadium based formulation;
• the second catalyst formulation is a copper-zeolite formulation;
• and
• the third catalyst formulation is an iron-zeolite formulation, wherein exposing the exhaust gas to the first and second catalyst formulations of the SCR catalyst results at high exhaust gas temperatures results in a decrease in N2O formation over an SCR catalyst including the second catalyst formulation alone.

A method for treating an exhaust gas, comprising:

• exposing the exhaust gas to a selective catalytic reduction (SCR) catalyst including first catalyst formulation and a second catalyst formulation;
• wherein the first catalyst formulation produces less N2O during NOx reduction by the SCR catalyst than the second formulation, and further comprising a third catalyst formulation on the SCR catalyst, wherein:
• the first catalyst formulation is a vanadium based formulation;
• the second catalyst formulation is a copper-zeolite formulation;
• the third catalyst formulation is an iron-zeolite formulation;
• the first catalyst formulation includes a low copper loading that is less than 75% copper;
• and
• the second catalyst formulation includes a high copper loading that is more than 75% copper.

A method for treating an exhaust gas, comprising:

• exposing the exhaust gas to a selective catalytic reduction (SCR) catalyst including first catalyst formulation and a second catalyst formulation;
• wherein the first catalyst formulation produces less N2O during NOx reduction by the SCR catalyst than the second formulation, and further comprising a third catalyst formulation on the SCR catalyst, wherein:
• the first catalyst formulation is a vanadium based formulation;
• the second catalyst formulation is a copper-zeolite formulation;
• the third catalyst formulation is an iron-zeolite formulation;
• the selective catalytic reduction (SCR) catalyst includes a first portion with the first formulation and a second portion with the second formulation;
• the first portion is positioned upstream of the second portion so the first portion first receives the exhaust gas.

A system, comprising:

• an internal combustion engine having an exhaust aftertreatment system for receiving an exhaust gas produced from operation of the internal combustion engine;
• a reductant system including a reductant source;
• and
• a diesel exhaust aftertreatment system that includes at least one selective catalytic reduction (SCR) catalyst positioned downstream of a connection of the reductant source to the exhaust aftertreatment system,
• the selective catalytic reduction (SCR) catalyst including a top washcoat and a bottom washcoat, wherein:
• the bottom washcoat includes a high copper loading SCR catalyst formulation;
• the top washcoat includes a low copper loading SCR catalyst formulation and substantially coats the bottom washcoat;
• further comprising a third catalyst formulation on the SCR catalyst, wherein;
• the top washcoat includes a vanadium based catalyst formulation;
• the bottom washcoat is a copper-zeolite catalyst formulation;
• and
• the third catalyst formulation is an iron-zeolite catalyst formulation.

A method for treating an exhaust gas, comprising:

• exposing the exhaust gas to a selective catalytic reduction (SCR) catalyst, the selective catalytic reduction (SCR) catalyst including a top washcoat and a bottom washcoat, and further comprising a third catalyst formulation on the SCR catalyst, wherein:
• the bottom washcoat includes a high copper loading SCR catalyst formulation;
• the top washcoat includes a low copper loading SCR catalyst formulation and substantially coats the bottom washcoat;
• the top washcoat includes a vanadium based catalyst formulation;
• the bottom washcoat is a copper-zeolite catalyst formulation;
• and
• the third catalyst formulation is an iron-zeolite catalyst formulation.