Iron (III) orthophosphate-carbon composite
AssigneeChemische Fabrik Budenheim KG
InventorsGunnar Buehler, Killian Schwarz, Andreas Jazdanian, Christian Graf, Michael Rapphahn
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Abstract
A method for producing an iron(III)orthophosphate-carbon composite which contains iron(III)orthophosphate of the general formula FePO4×nH2O (n≦2.5), a carbon source being dispersed in a phosphoric aqueous Fe2+ ion-containing solution and orthophosphate-carbon composite being precipitated and removed from the aqueous solution when an oxidant is added to the dispersion.
Claims36
A method for the production of an iron(III) orthophosphate-carbon composite that contains iron(III) orthophosphate-carbon composite that contains iron(III) orthophosphate of the general formula FePO4×nH2O (n<2.5) comprising:
- dispersing a carbon source in a phosphoric acid aqueous Fe2+ ion-containing aqueous solution to obtain a dispersion, wherein the aqueous Fe2+ ion-containing solution is prepared by adding iron(II), iron(III) or mixed iron(II,III) compounds, selected from the group consisting of hydroxides, oxides, oxide-hydroxides, hydrated oxides, carbonates, hydroxide carbonates and mixtures thereof, together with elementary iron, to a phosphoric acid-containing aqueous medium to bring Fe2+ ions into solution and to convert Fe3+ with the elementary Fe, by a comproportionation reaction, to Fe2+ and then separating solids from the phosphoric acid aqueous Fe2+solution, adding an oxidizing agent to the dispersion to precipitate the iron(III) orthophosphate-carbon composite from the aqueous solution, and separating the iron(III) orthophosphate-carbon composite precipitate from the aqueous solution, wherein the iron(III) orthophosphate-carbon composite contains iron(III) orthophosphate of the general formula FePO4×nH2O (n<2.5).
Iron(III) orthophosphate-carbon composite produced according to a method comprising:
- dispersing a carbon source in a phosphoric acid aqueous Fe2+ ion-containing aqueous solution to obtain a dispersion,wherein the aqueous Fe2+ ion-containing solution is prepared by adding iron (II), iron (III) or mixed iron (II,III) compounds, selected from the group consisting of hydroxides, oxides, oxide-hydroxides, hydrated oxides, carbonates, hydroxide carbonates and mixtures thereof, together with elementary iron, to a phosphoric acid-containing aqueous medium to bring Fe2+ ions into solution and to convert Fe3+ with the elementary Fe, by a comproportionation reaction, to Fe2+ and then separating solids from the phosphoric acid aqueous Fe2+ solution,
- adding an oxidizing agent to the dispersion to precipitate the iron(III) orthophosphate-carbon composite from the aqueous solution, and
- separating the iron(III) orthophosphate-carbon composite precipitate from the aqueous solution,
- wherein the iron(III) orthophosphate-carbon composite contains iron(III) orthophosphate of the general formula FePO4×nH2O (n≦2.5).
Dependencies are inferred from the claim text.