Use of tetrahydroberizoxazines as stabilisers
AssigneeBASF SE
InventorsArno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
Life of this patent
Estimating the term…
Abstract
The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.
Claims10
An antioxidant for stabilizing mineral oil products and fuels against the action of light, oxygen and heat, comprising:
- a tetrahydrobenzoxazine of formula I
- wherein
- R1 is a polyisobutene having a Mn of from 200 to 40,000,
- R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals which have in each case from 1 to 3000 carbon atoms optionally having one or more heteroatoms from the group of O and S and/or one or more NR6 moieties,
- wherein the substituent R4 may also be a radical of the formula Y
- wherein R2, R3 and R5 are each as defined above and X is a hydrocarbon bridging element which consists of one or more isobutene units or comprises one or more isobutene units, or
- wherein the substituent R4 may also be a radical of the formula Z or Z′
- (Z)
- wherein R2, R3 and R5 are each as defined above and R10, R11 and R12 are independently hydrogen or a C1- to C10-alkyl radical,
- and wherein R2 and R3 or R3 and R4 or R4 and R5, together with the part-structure —O—CH2—NR7—CH2— attached to the benzene ring, may also form a second tetrahydrooxazine ring, or the substituents R2 and R3 and R4 and R5, together with the part-structures —O—CH2—NR7—CH2— and —O—CH2—NR8—CH2— attached to the benzene ring, may also form a second and a third tetrahydrooxazine ring,
- wherein R7 and R8 are each independently hydrocarbyl radicals which have in each case from 1 to 3000 carbon atoms and optionally have one or more heteroatoms from the group of O and S and/or one or more NR6 moieties.
Dependencies are inferred from the claim text.