Chemically amplified negative resist composition, photo-curable dry film, making method, pattern forming process, and electric/electronic part protecting film
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsKatsuya Takemura, Takeru Watanabe, Takashi Miyazaki
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Abstract
A chemically amplified negative resist composition is provided comprising (A) a resin having a crosslinking group, (B) a crosslinker, (C) a photoacid generator capable of generating an acid upon exposure to light of wavelength 190-500 nm, (D) a solvent, and (E) a fluoroalkyl-containing amine compound. The resist composition can form a fine pattern, specifically a fine hole or space pattern which has a positive taper (or forward taper) profile in which the size of top is greater than the size of bottom or improves the overhang profile with extremely projected top.
Claims11
A chemically amplified negative resist composition comprising
- (A) a resin having a crosslinking group or a reaction site susceptible to crosslinking reaction within the molecule,
- (B) a crosslinker,
- (C) a photoacid generator which is decomposed to generate an acid upon exposure to light of wavelength 190 to 500 nm,
- (D) a solvent, and
- (E) at least one amine compound having a fluoroalkyl Group and a morpholine structure
- wherein component (A) is a silicone structure-bearing polymer comprising recurring units of the general formula (1) and having a weight average molecular weight of 3,000 to 500,000,
- wherein R1 to R4 are each independently a monovalent C1-C8 hydrocarbon group, m is an integer of 1 to 100, a, b, c and d each are 0 or a positive number, with the proviso that a, b, c and d are not equal to 0 at the same time, and a+b+c+d=1,
- X is a divalent organic group of the general formula (2):
- wherein Z is a divalent organic group selected from the following:
- n is 0 or 1, R5 and R6 are each independently C1-C4 alkyl or alkoxy, and k is 0, 1, or 2, and
- Y is a divalent organic group of the general formula (3):
- wherein V is a divalent organic group selected from the following:
- p is 0 or 1, R7 and R8 are each independently C1-C4 alkyl or alkoxy, and h is 0, 1, or 2, and
- component (B) is at least one crosslinker selected from the group consisting of an amino condensate modified with formaldehyde or formaldehyde-alcohol, a phenol compound having on the average at least two methylol or alkoxymethylol groups in the molecule, and a polyhydric phenol compound having a hydroxyl group substituted by a glycidoxy group.
Dependencies are inferred from the claim text.