Ethylenically unsaturated polymerizable groups comprising polycarbosiloxane monomers

An article of manufacture selected from the group consisting of contact lenses, phakic and aphakic intraocular lenses and corneal implants;

• wherein the article is formed from polymerizing a monomer mixture including an ethylenically unsaturated free radical polymerizable polycarbosiloxane monomer of formula (I) and at least a second free radical copolymerizable monomer, wherein the polycarbosiloxane monomer of formula (I) is present at from about 0.1 to about 30 percent by weight of the monomer mixture:
• wherein R1, R2, R4, R5, R6, R7, R8, R11, R12, R13, R14, R15 and R16 are each independently a monovalent atom or group selected from H, alkyl, halo alkyl, heteroalkyl, cyclo alkyl, heterocyclo alkyl, alkenyl, halo alkenyl, or aromatic;
• wherein R3 is a monovalent atom or group selected from H, alkyl, halo alkyl, heteroalkyl, cyclo alkyl, heterocyclo alkyl, alkenyl, halo alkenyl, aromatic or methacryloxypropyl;
• wherein at least one of R9 or R10 is hydrogen, and the other of R9 and R10 may not be present when monomers of formula (I) comprise -[silyl-alkenyl-siloxy]- units, and when present in a monomer comprising -[silyl-alkyl-siloxy]- units is independently a monovalent atom or group selected from H, alkyl, alkene, alkyne;
• y is 2-7;
• n is 1-100;
• n1 is greater than zero and up to 10;
• L is the same or different and is a divalent linker group or a bond;
• and V is an ethylenically unsaturated free radical polymerizable monovalent group.