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US 9,006,136 B2Granted
Highly porous activated carbon with controlled oxygen content
AssigneeCorning Incorporated
InventorsKishor Purushottam Gadkaree, Jia Liu
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Abstract
Nanoporous activated carbon material having a high specific capacitance in EDLCs and controlled oxygen content, and methods for making such activated carbon material. Reduction of oxygen content is achieved by (a) curing a carbon precursor/additive mixture in an inert or reducing environment, and/or (b) refining (heating) activated carbon material after synthesis in an inert or reducing environment. The inert or reducing environment used for curing or refining is preferably substantially free of oxygen.
Claims4
A porous activated carbon material formed according to a method, comprising:
- forming a mixture of a carbon precursor selected from the group consisting of a synthetic polymer thermosetting resin and a synthetic polymer thermoplastic resin and an inorganic compound selected from the group consisting of KOH, K2CO3, KCl, NaOH, Na2CO3, NaCl, P2O5, AlCl3, MgCl2, ZnCl2 and H3PO4;
- heating the mixture at a first temperature to cure the carbon precursor;
- heating the cured carbon precursor at a second temperature higher than the first temperature to carbonize the carbon precursor and produce an activated carbon material, wherein the method further comprises:
- (a) heating the mixture at the first temperature in a nitrogen environment, and
- (b) washing the activated carbon to remove the inorganic compound and then heating the washed activated carbon material at a third temperature ranging from about 450° C. to 1000° C. in an environment that is substantially free of oxygen to refine the activated carbon material, wherein the activated carbon material comprises 7 to 8 wt. % oxygen and at least one of a microporous volume of 0.65 to 0.67 cm3/g and a total pore volume of 0.75 to 0.78 cm3/g.
2 more elements
Dependencies are inferred from the claim text.