Carbazole polymer
AssigneeNissan Chemical Industries, Ltd.
InventorsYuki Shibano, Takuji Yoshimoto
Life of this patent
Estimating the term…
Abstract
A carbazole polymer including a repeating unit represented by Formula 1 and having excellent one electron oxidation-state stability, wherein, in Formula 1, R1-R4 each independently represents an alkyl group having 1-60 carbon atoms, a haloalkyl group having 1-60 carbon atoms, or similar, Cz represents a divalent group including a carbazole skeleton represented by Formula 2, and Ar represents a divalent aromatic ring or similar; wherein, in Formula 2, R5 represents a hydrogen atom, an alkyl group having 1-60 carbon atoms, or similar, R6-R11 each independently represents a hydrogen atom, a halogen atom, or similar, and m represents an integer 1-10.
Claims22
A carbazole polymer characterized by comprising recurring units of formula (1)
- in formula (1), R1 to R4 are each independently an alkyl group of 1 to 60 carbons, a haloalkyl group of 1 to 60 carbons, a cycloalkyl group of 3 to 60 carbons, a bicycloalkyl group of 4 to 60 carbons, an alkenyl group of 2 to 60 carbons, an alkynyl group of 2 to 60 carbons, an aromatic group of 6 to 60 carbons or a heteroaromatic group of 2 to 60 carbons which alkyl, haloalkyl, cycloalkyl, bicycloalkyl, alkenyl, alkynyl, aromatic and heteroaromatic groups may be substituted with Z;
- Cz is a divalent group that includes the carbazole skeleton of formula (2)
- in formula (2), R5 being a hydrogen atom, an alkyl group of 1 to 60 carbons, a haloalkyl group of 1 to 60 carbons, a cycloalkyl group of 3 to 60 carbons, a bicycloalkyl group of 4 to 60 carbons, an alkenyl group of 2 to 60 carbons, an alkynyl group of 2 to 60 carbons, an aromatic group of 5 to 59 carbons or a heteroaromatic group of 2 to 60 carbons which alkyl, haloalkyl, cycloalkyl, bicycloalkyl, alkenyl, alkynyl, aromatic and heteroaromatic groups may be substituted with Z, and which alkyl groups and haloalkyl groups may include an ether structure,
- R6 to R11 being each independently a hydrogen atom, a halogen atom, a nitro group, a cyano group, an amino group, a hydroxyl group, a thiol group, a phosphate group, a sulfonic acid group, a carboxyl group, an alkoxy group of 1 to 60 carbons, a thioalkoxy group of 1 to 60 carbons, an alkyl group of 1 to 60 carbons, a haloalkyl group of 1 to 60 carbons, a cycloalkyl group of 3 to 60 carbons, a bicycloalkyl group of 4 to 60 carbons, an alkenyl group of 2 to 60 carbons, an alkynyl group of 2 to 60 carbons, an acyl group of 1 to 60 carbons, an aromatic group of 6 to 60 carbons or a heteroaromatic group of 2 to 60 carbons which alkoxy, thioalkoxy, alkyl, haloalkyl, cycloalkyl, bicycloalkyl, alkenyl, alkynyl, acyl, aromatic and heteroaromatic groups may be substituted with Z, and
- m being an integer from 1 to 10;
- Ar is a divalent aromatic ring or heteroaromatic ring which aromatic and heteroaromatic rings may be substituted with Z;
- and
- Z is a halogen atom, a nitro group, a cyano group, an amino group, a hydroxyl group, a thiol group, a phosphate group, a sulfonic acid group, a carboxyl group, an alkoxy group of 1 to 60 carbons, a thioalkoxy group of 1 to 60 carbons, an alkyl group of 1 to 60 carbons, a haloalkyl group of 1 to 60 carbons, a cycloalkyl group of 3 to 60 carbons, a bicycloalkyl group of 4 to 60 carbons, an alkenyl group of 2 to 60 carbons, an alkynyl group of 2 to 60 carbons, an acyl group of 1 to 60 carbons, an aromatic group of 6 to 60 carbons or a heteroaromatic group of 2 to 60 carbons.
Dependencies are inferred from the claim text.