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US 8,785,578 B2Granted
Paper coatings of amphiphilic, non-water-soluble comb-branched (meth)acrylic polymers, uses thereof
AssigneeCoatex
InventorsJean-Marc Suau, Murielle Guillot
Life of this patent
Estimating the term…
Abstract
Polymers, paper coating compositions, and coated paper.
Claims19
A polymer comprising, expressed as a % by weight of each of the monomers, polymerized units of the following monomers:
- a) 30% to 60% of at least one hydroxy- and/or methoxy-polyalkylene glycol monomer, with the formula R-(EO)m-(PO)n-R′, where:
- m and n designate integers less than or equal to 150, at least one of which is non-zero,
- EO and PO respectively designate ethylene oxide and propylene oxide,
- R designates a methacrylate or methacrylurethane function, and
- R′ designates a hydrogen radical or a methyl radical,
- b) 48% to 60% of at least one monomer selected from the group consisting of styrene and (meth)acrylic esters whose ester portion has 1 to 4 carbon atoms,
- c) 0.1% to 10% of at least one of acrylic acid and methacrylic acid,
- d) 0 to 5% of a monomer whose formula is R-(EO)m-(PO)n-R″, where:
- m and n designate integers less than or equal to 150, at least one of which is non-zero,
- EO and PO respectively designate ethylene oxide and propylene oxide,
- R designates a methacrylate or methacrylurethane function,
- R″ designates an alkyl or aryl or alkylaryl group having 8 to 32 linear or branched carbon atoms,
- e) 0 to 5% of a monomer comprising two ethylenic unsaturations,
- the sum of a), b), c), d), and e) being equal to 100%,
- wherein said polymer is non-water-soluble in acid form.
12 more elements
A paper coating composition comprising a mineral material and:
- 1) 3 parts to 20 parts by weight of a binder per 100 parts by dry weight of mineral material,
- 2) 0.1 parts to 2 parts by weight of a polymer per 100 parts by dry weight of mineral material, and
- 3) water in a quantity by weight of between 20% and 80%, compared to the total weight of the paper coating composition,
- wherein said polymer is a polymer comprising, expressed as a % by weight of each of the monomers, polymerized units of the following monomers:
- a) 30% to 60% of at least one hydroxy- and/or methoxy-polyalkylene glycol monomer, with the formula R-(EO)m-(PO)n-R′, where:
- m and n designate integers less than or equal to 150, at least one of which is non-zero,
- EO and PO respectively designate ethylene oxide and propylene oxide,
- R designates a methacrylate or methacrylurethane function, and
- R′ designates a hydrogen radical or a methyl radical,
- b) 48% to 60% of at least one monomer selected from the group consisting of styrene and (meth)acrylic esters whose ester portion has 1 to 4 carbon atoms,
- c) 0.1% to 10% of at least one of acrylic acid and methacrylic acid,
- d) 0 to 5% of a monomer whose formula is R-(EO)m-(PO)n-R″, where:
- m and n designate integers less than or equal to 150, at least one of which is non-zero,
- EO and PO respectively designate ethylene oxide and propylene oxide,
- R designates a methacrylate or methacrylurethane function,
- R″ designates an alkyl or aryl or alkylaryl group having 8 to 32 linear or branched carbon atoms,
- e) 0 to 5% of a monomer comprising two ethylenic unsaturations,
- the sum of a), b), c), d), and e) being equal to 100%,
- wherein said polymer is non-water-soluble in acid form.
16 more elements
Dependencies are inferred from the claim text.