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US 8,785,558 B2Granted
Process for the production of condensation polymers via in-reactor chain extension and products thereof
AssigneeBASF SE
InventorsGary A. Deeter, Marco A. Villalobos
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Abstract
Methods for forming high molecular weight chain-extended condensation polymers are disclosed. The methods include adding a chain extender during the polymerization process of a condensation polymer to provide a chain-extended condensation polymer, wherein the chain extender comprises a polymerization product of at least one epoxy-functional (meth)acrylic monomer, and at least one styrenic and/or (meth)acrylic monomer.
Claims11
A method comprising:
- adding a chain extender during the polymerization process of a condensation polymer to provide a chain-extended condensation polymer, wherein the chain extender comprises a polymerization product of
- at least one functional (meth)acrylic monomer, and
- at least one styrene monomer, substituted styrene monomer, (meth)acrylic monomer, or a mixture of any two or more thereof;
- wherein:
- the chain extender is added from about 0.1% to about 0.32% by weight of the total weight of the chain extender and the components of the condensation polymer;
- and the condensation polymer is polyethyleneterephthalate.
3 more elements
A method comprising:
- adding a chain extender during the polymerization process of a polyester to provide a chain-extended polyester, wherein the chain extender comprises a polymerization product of
- at least one epoxy-functional (meth)acrylic monomer, and
- at least one styrene monomer, substituted styrene monomer, (meth)acrylic monomer, or a mixture of any two or more thereof;
- wherein:
- the polymerization process is a batch polymerization process or a continuous polymerization process;
- the chain extender is added when the solution intrinsic viscosity of the condensation polymer is no more than about 0.6 dL/g;
- and
- a molecular weight of the chain-extended condensation polymer is achieved in a time that is less than the time to achieve the molecular weight in the absence of the chain extender;
- the chain extender is added from about 0.1% to about 0.32% by weight of the total weight of the chain extender and the components of the polyester;
- and
- the polyester is polyethyleneterephthalate.
8 more elements
Dependencies are inferred from the claim text.