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US 8,785,557 B2Granted
Use of aqueous hybrid binders for gloss paints
AssigneeBASF SE
InventorsSebastian Roller, Roelof Balk, Rolf Dersch
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Abstract
The present invention relates to the use of aqueous hybrid binders for producing coating compositions, more particularly in high-gloss coating materials (high-gloss paints), and also to a process for their preparation with low residual monomer content.
Claims12
A process for preparing an aqueous acrylate-alkyd polymer dispersion (PD) by free-radical emulsion polymerization of
- (a) at least one α,β-ethylenically unsaturated monomer (M),
- (b) and at least one further monomer (M1) selected from the group consisting of esters of α,β-ethylenically unsaturated monocarboxylic and dicarboxylic acids with C1-C20 alkanols, vinylaromatics, esters of vinyl alcohol with C1-C30monocarboxylic acids, ethylenically unsaturated nitriles, vinyl halides, vinylidene halides, and mixtures thereof, to give a polymer (P),
- (c) optionally, subsequent chemical deodorization and
- (d) addition of at least one water-soluble alkyd resin having a weight-average molecular weight of between 5000 and 40,000 Da, or of at least one aqueous alkyd emulsion or polyurethane-alkyd emulsion,
- which comprises adding the alkyd resin or the alkyd emulsion or polyurethane-alkyd emulsion, the temperature at addition being 60 to 99° C., either subsequent to the polymerization of M and M1, with an afterstir time of 0-2 h or subsequent to the chemical deodorization when carried out, with an afterstir time of 0-2 h.
2 more elements
Dependencies are inferred from the claim text.