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US 8,785,548 B2Granted
Styrenic (meth)acrylic oligomers
AssigneeBASF SE
InventorsTimothy D. Klots, Rafael Galvan, Jon Debling
Life of this patent
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Abstract
Styrenic (meth)acrylic oligomers that are prepared at lower temperature than conventional solid grade oligomers, or are hydrogenated, contain fewer terminal vinylic unsaturations, when compared to such conventional styrenic (meth)acrylic oligomers prepared by the customary high temperature processes. Styrenic (meth)acrylic oligomers that contain fewer terminal vinylic unsaturations demonstrate improved thermal stability and may provide improved resistance to UV weathering compared to the conventional and non-hydrogenated styrenic (meth)acrylic oligomers.
Claims16
A process comprising:
- continuously charging into a reactor a mixture comprising:
- about 20 wt % to about 80 wt % of a vinylic monomer, the vinylic monomer comprising a styrenic monomer, a (meth)acrylic monomer, or a mixture thereof;
- about 0.25 wt % to about 5 wt % of a polymerization initiator;
- and
- about 20 wt % to about 80 wt % of a reaction solvent;
- maintaining the reactor at a temperature of from about 120° C. to about 165° C. to produce an oligomer from the vinylic monomer;
- and
- isolating the oligomer;
- wherein:
- the oligomer has an insubstantial amount of olefinic unsaturation and a residence time of the oligomer in the reactor is from about 5 minutes to about 60 minutes.
7 more elements
Dependencies are inferred from the claim text.