Sensitizer for cationic photoinitiators
AssigneeSun Chemical Corporation
InventorsShaun Lawrence Herlihy, Robert Stephen Davidson
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Abstract
Polycyclic aromatic compounds of formula (I) having at least two conjugated aromatic rings at least one of which has a substituent comprising a cyclic carbonate group can be used as sensitizers for cationic photoinitiators, especially iodonium compounds, and may also function as monomers in cationically initiated radiation curable compositions, especially coating compositions, such as printing inks and varnishes.
Claims20
A composition comprising an iodonium salt cationic photoinitiator and a polycyclic aromatic compound having the formula (I):
- in which:
- Q represents a residue of a polycyclic aromatic compound having at least two conjugated aromatic rings and having a valency x;
- Y is an aliphatic carbon chain which may be interrupted by one or more oxygen atoms, sulphur atoms, phenylene groups, carbonyl groups, epoxide groups or linear or cyclic carbonate groups;
- p is 0 or 1;
- R1 and R2 are the same as or different from each other, and each represents a hydrogen atom, an alkyl group, a hydroxyalkyl group, an alkoxyalkyl group, an alkoxycarbonylalkyl group or a C2-C5 carbon chain which is attached to a carbon atom of Y to form a fused ring;
- R1 represents a hydrogen atom or an alkyl group;
- and
- m and n are the same as or different from each other, and each is zero or a number from 1 to 4, provided that (m+n) is zero or a number from 1 to 4.
A composition according to 4, in which the conjugated aromatic ring is a naphthalene or anthracene ring system, which is substituted or unsubstituted.
Dependencies are inferred from the claim text.