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US 8,785,105 B2Granted
Sulfonium salt-containing polymer, resist composition, patterning process, and sulfonium salt monomer and making method
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsYouichi Ohsawa, Masaki Ohashi, Seiichiro Tachibana, Jun Hatakeyama
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Abstract
A sulfonium salt having a 4-fluorophenyl group is introduced as recurring units into a polymer comprising hydroxyphenyl (meth)acrylate units and acid labile group-containing (meth)acrylate units to form a polymer which is useful as a base resin in a resist composition. The resist composition has a high sensitivity, high resolution and minimized LER.
Claims16
A polymer comprising recurring units having the general formulae (1a), (2), and (3):
- wherein
- R1 is hydrogen, fluorine, methyl or trifluoromethyl,
- R2, R3, and R4 are each independently a substituted or unsubstituted, straight or branched C1-C10 alkyl, alkenyl or oxoalkyl group, a substituted or unsubstituted C6-C18 aryl, aralkyl or aryloxoalkyl group, or 4-fluorophenyl group, any two of R2, R3, and R4 may bond together to form a ring with the sulfur atom, with the proviso that at least one of R2, R3, and R4 is a 4-fluorophenyl group,
- n is an integer of 0 to 2,
- R8 is hydrogen or a C1-C10 alkyl group,
- p is 0 or 1,
- B is a single bond or a C1-C10 divalent organic group which may be substituted with an oxygen atom,
- a is an integer of 0 to 3,
- b is an integer of 1 to 3, and
- X is an acid labile group.
7 more elements
Dependencies are inferred from the claim text.