A polymer electrolyte fuel cell separator made of pure titanium or a titanium alloy having a surface layer part to which conductive compound particles are affixed, said polymer electrolyte fuel cell separator made of pure titanium or a titanium alloy characterized in that the pure titanium or titanium alloy has a surface oxide of a thickness of 3 to 15 nm in range, an average carbon concentration in a range from an outermost surface, including the oxide layer of the pure titanium or titanium alloy, to a depth of 100 nm is 0.4 to 6 at %, and said conductive compound particles have an average particle size of 0.01 to 20 μm and a density per unit area at a separator surface part of 1×108/cm2 or more, wherein said conductive compound particles comprise one or more of Cr2N, CrSi2, VB, V8C7, VN, TaN, TaC, and WN.