Back to results
US 8,772,408 B2Granted
Binders containing nanoparticles
AssigneeBayer Intellectual Property GmbH
InventorsThomas Münzmay, Michael Mager, Markus Mechtel, Nusret Yuva
Life of this patent
Estimating the term…
Abstract
The present invention relates to aqueous binder dispersions based on silane-modified polymeric binders and inorganic nanoparticles, a process for the preparation thereof and the use thereof for the production of high quality coatings, in particular clear lacquers.
Claims5
A method for stabilizing inorganic nanoparticles, wherein the method comprises forming an aqueous formulation comprising
- A) a silane-modified copolymer comprising groups of general formula (1)
- —Si(R1O)2R2 (1)
- wherein
- R1 is a C2- to C8-alkyl radical;
- and
- R2 is (R1O) or a C1- to C5-alkyl radical,
- built up from
- I) a hydroxy-functional hydrophobic polymer containing as builder monomers
- Ia) (meth)acrylic acid esters having C1- to C18-hydrocarbon radicals in the alcohol part and/or vinylaromatics and/or vinyl esters;
- Ib) hydroxy-functional monomers;
- and
- IS1) silane-functional monomers capable of polymerization;
- and
- II) a hydroxy-functional hydrophilic polymer containing as builder components
- IIa) (meth)acrylic acid esters having C1- to C18-hydrocarbon radicals in the alcohol part and/or vinylaromatics and/or vinyl esters;
- IIb) hydroxy-functional monomers;
- and
- IIc) acid-functional monomers;
- B) inorganic particles which are optionally surface-modified, and having an average particle size (z-mean), as determined by means of dynamic light scattering in dispersion, of less than 200 nm, wherein said inorganic particles B) are inorganic nanoparticles in a colloidally disperse form in organic solvents or in water;
- and
- C) water;
- wherein the inorganic particles are introduced by mechanical stirring.
19 more elements
Dependencies are inferred from the claim text.