Fungicide pyrazole carboxamides derivates

A compound of formula (I)

• wherein
• Y is selected from the group consisting of CR5 and N;
• T is selected from the group consisting of S and O;
• X1 and X2 are independently selected from the group consisting of chlorine and fluorine;
• Z1 is selected from the group consisting of a non substituted cyclopropyl and a cyclopropyl substituted by up to 2 atoms or groups independently selected from the group consisting of halogen;
• cyano;
• C1-C8-alkyl;
• and C1-C8-halogenoalkyl comprising up to 9 halogen atoms that can be the same or different;
• Z2 and Z3 are independently selected from the group consisting of hydrogen;
• substituted or non substituted C1-C8-alkyl;
• substituted or non substituted C2-C8-alkenyl;
• substituted or non substituted C2-C8-alkynyl;
• cyano;
• isonitrile;
• nitro;
• halogen;
• substituted or non substituted C1-C8-alkoxy;
• substituted or non substituted C2-C8-alkenyloxy;
• substituted or non substituted C2-C8-alkynyloxy;
• substituted or non substituted C3-C7-cycloalkyl;
• substituted or non substituted C1-C8-alkylsulfanyl;
• substituted or non substituted C1-C8-alkylsulfonyl;
• substituted or non substituted C1-C8-alkylsulfinyl;
• amino;
• substituted or non substituted C1-C8-alkylamino;
• substituted or non substituted di-C1-C8-alkylamino;
• substituted or non substituted C1-C8-alkoxycarbonyl;
• substituted or non substituted C1-C8-alkylcarbamoyl;
• substituted or non substituted di-C1-C8-alkylcarbamoyl;
• and substituted or non substituted N—C1-C8-alkyl-C1-C8-alkoxycarbamoyl;
• or
• Z3 and R1 together with the consecutive carbon atoms to which they are linked form a substituted or non substituted 5-, 6- or 7-membered, partly saturated, carbo- or hetero-cycle comprising up to 3 heteroatoms and Z2 is as herein described;
• or
• Z2 and Z3 together with the carbon atom to which they are linked form a substituted or non substituted C3-C7 cycloalkyl;
• R1, R2, R3, R4 and R5 are independently selected from the group consisting of hydrogen halogen;
• nitro;
• cyano;
• isonitrile;
• hydroxyl;
• sulfanyl;
• amino;
• pentafluoro-λ6-sulfanyl;
• substituted or non substituted C1-C8-alkyl;
• C1-C8-halogenoalkyl comprising up to 9 halogen atoms which can be the same or different;
• substituted or non substituted C1-C8-alkylamino;
• substituted or non substituted di-C1-C8-alkylamino;
• substituted or non substituted C1-C8-alkoxy;
• C1-C8-halogenoalkoxy comprising up to 9 halogen atoms which can be the same or different;
• C1-C8-alkoxy-C1-C8-alkyl;
• substituted or non substituted C1-C8-alkylsulfanyl;
• C1-C8-halogenoalkylsulfanyl comprising up to 9 halogen atoms which can be the same or different;
• substituted or non substituted C2-C8-alkenyl;
• C2-C8-halogenoalkenyl comprising up to 9 halogen atoms which can be the same or different;
• substituted or non substituted C2-C8-alkynyl;
• C2-C8-halogenoalkynyl comprising up to 9 halogen atoms which can be the same or different;
• substituted or non substituted C2-C8-alkenyloxy;
• C2-C8-halogenoalkenyloxy comprising up to 9 halogen atoms which can be the same or different;
• substituted or non substituted C2-C8-alkynyloxy;
• C2-C8-halogenoalkynyloxy comprising up to 9 halogen atoms which can be the same or different;
• substituted or non substituted C3-C7-cycloalkyl;
• C3-C7-halogenocycloalkyl comprising up to 9 halogen atoms which can be the same or different;
• substituted or non substituted C3-C7-cycloalkyl-C1-C8-alkyl;
• substituted or non substituted C3-C7-cycloalkyl-C2-C8-alkenyl;
• substituted or non substituted C3-C7-cycloalkyl-C2-C8-alkynyl;
• substituted or non substituted C3-C7-cycloalkyl-C3-C7-cycloalkyl;
• substituted or non substituted C1-C8 alkyl-C3-C7-cycloalkyl;
• formyl;
• formyloxy;
• formylamino;
• carboxy;
• carbamoyl;
• N-hydroxycarbamoyl;
• carbamate;
• (hydroxyimino)-C1-C8-alkyl;
• substituted or non substituted C1-C8-alkylcarbonyl;
• C1-C8-halogenoalkylcarbonyl comprising up to 9 halogen atoms which can be the same or different;
• substituted or non substituted C1-C8-alkylcarbamoyl;
• substituted or non substituted di-C1-C8-alkylcarbamoyl;
• N-(substituted or non substituted C1-C8 alkyloxy)carbamoyl;
• substituted or non substituted C1-C8-alkoxycarbamoyl;
• N-(substituted or non substituted C1-C8-alkyl)-(substituted or non substituted C1-C8-alkoxy)-carbamoyl;
• substituted or non substituted C1-C8-alkoxycarbonyl;
• C1-C8-halogenoalkoxycarbonyl comprising up to 9 halogen atoms which can be the same or different;
• substituted or non substituted C1-C8-alkylaminocarbonyl;
• di-substituted or non substituted C1-C8-alkylaminocarbonyl;
• substituted or non substituted C1-C8-alkylcarbonyloxy;
• C1-C8-halogenoalkylcarbonyloxy comprising up to 9 halogen atoms which can be the same or different;
• substituted or non substituted C1-C8-alkylcarbonylamino;
• C1-C8-halogenoalkylcarbonylamino comprising up to 9 halogen atoms which can be the same or different;
• substituted or non substituted C1-C8-alkylaminocarbonyloxy;
• substituted or non substituted di-C1-C8-alkylaminocarbonyloxy;
• substituted or non substituted C1-C8-alkyloxycarbonyloxy;
• substituted or non substituted C1-C8-alkylsulfinyl;
• C1-C8-halogenoalkylsulfinyl comprising up to 9 halogen atoms which can be the same or different;
• substituted or non substituted C1-C8-alkylsulfonyl;
• C1-C8-halogenoalkylsulfonyl comprising up to 9 halogen atoms which can be the same or different;
• substituted or non substituted C1-C8-alkoxyimino;
• (C1-C8-alkoxyimino)-C1-C8-alkyl;
• substituted or non substituted (C1-C8-alkenyloxyimino)-C1-C8-alkyl;
• (C1-C8-alkynyloxyimino)-C1-C8-alkyl;
• a (benzyloxyimino)-C1-C8-alkyl;
• tri(substituted or non substituted C1-C8-alkyl)silyl;
• tri(substituted or non substituted C1-C8-alkyl)silyl-C1-C8-alkyl;
• benzyloxy which can be substituted by up to 5 groups Q;
• benzylsulfanyl which can be substituted by up to 5 groups Q;
• benzylamino which can be substituted by up to 5 groups Q;
• aryl which can be substituted by up to 7 groups Q;
• aryloxy which can be substituted by up to 7 groups Q;
• arylamino which can be substituted by up to 7 groups Q;
• arylsulfanyl which can be substituted by up to 7 groups Q;
• aryl-C1-C8 alkyl which can be substituted by up to 7 groups Q;
• aryl-C2-C8-alkenyl which can be substituted by up to 7 groups Q;
• aryl-C2-C8-alkynyl which can be substituted by up to 7 groups Q;
• pyridinyl which can be substituted by up to 4 groups Q;
• pyridinyloxy which can be substituted by up to 4 groups Q;
• and aryl-C3-C7-cycloalkyl which can be substituted by up to 7 groups Q;
• or
• Two vicinal substituents R together with the consecutive carbon atoms to which they are linked form a substituted or non substituted 5- or 6-membered, saturated, carbo- or hetero-cycle comprising up to 3 heteroatoms and the other substituents R are as herein-described;
• or
• R1 and Z3 together with the consecutive carbon atoms to which they are linked form a substituted or non substituted 5-, 6- or 7-membered, partly saturated, carbo- or hetero-cycle comprising up to 3 heteroatoms, and R2 to R5 are as herein-described;
• Each Q is independently selected from the group consisting of halogen;
• cyano;
• nitro;
• C1-C8-alkyl;
• C1-C8-alkoxy;
• C1-C8-alkylsulfanyl;
• C1-C8-halogenoalkyl comprising up to 9 halogen atoms which can be the same or different;
• C1-C8-halogenoalkoxy comprising up to 9 halogen atoms which can be the same or different;
• tri(C1-C8)alkylsilyl and tri(C1-C8)alkylsilyl-C1-C8-alkyl;
• with the proviso that when Y is N, and T is O, and Z1 is a cyclopropyl group, and R1 is chlorine, and R3 is a trifluoromethyl group, and R2 and R4 are both hydrogen, then at least one of the substituents Z2 or Z3 is not hydrogen;
• as well as salts, N-oxides, metallic complexes, metalloidic complexes and optically active or geometric isomers thereof.