US 8,771,924 B2 · Polymerizable composition, lithographic printing plate precursor and lithographic printing method

Abstract

A polymerizable composition contains a binder polymer containing a functional group having a dipole moment of 3.8 debye or more and being represented by the formula (1), (2), (3), (4) or (5) as defined herein, a radical polymerizable compound and a radical polymerization initiator.

Claims15

Dependent claims

A polymerizable composition comprising a binder polymer containing a functional group having a dipole moment of 4.5 debye or more, a radical polymerizable compound which is an addition polymerizable compound having at least one ethylenically unsaturated double bond, an infrared absorbing agent or a sensitizing dye having absorption in a wavelength of from 360 to 450 nm and a radical polymerization initiator,

wherein the functional group having a dipole moment of 4.5 debye or more is selected from the following groups:

A polymerizable composition comprising a binder polymer containing a functional group having a dipole moment of 3.8 debye or more and being represented by the following formula (1), (2), (3) (4) or (5), a radical polymerizable compound which is an addition polymerizable compound having at least one ethylenically unsaturated double bond and a radical polymerization initiator:

wherein X and Y each independently represents —C(R5)(R6)—, —C(R5)═, —O—, —S—, —N(R)5— or —N═, Z1 represents O or S, Z2 represents 0 or a lone pair, Z3 represents —C(R5)(R6)—, C(R5)═, —O—, —S—, —N(R5)— or —N═, R1 to R6 each independently represents a substituent comprising at least one atom selected from hydrogen, carbon, oxygen, nitrogen, sulfur, phosphorus, halogen and silicon or appropriate two of R1 to R6 may be combined with each other to form a ring, provided that at least one of R1 to R6 represents a divalent connecting group comprising at least one atom selected from hydrogen, carbon, oxygen, nitrogen, sulfur, phosphorus, halogen and silicon and connecting to a skeleton of the binder polymer,
wherein the functional group having a dipole moment of 3.8 debye or more and being represented by the formula (1), (2), (3), (4) or (5) is selected from the following groups:
Groups of Formula (2):
3.9
4.0
5.4
4.3
5.5
5.6
4.1
5.4
4.8
5.4
5.1
5.1
4.7
5.5
5.3
4.9
6.3
4.1
6.2
5.3
3.9
5.8
4.6
4.7
4.9
4.4
4.9
4.7
4.1
3.9
4.1
3.9
4.7
4.7
Grops of Formulae (3) to (5):
5.0
5.3
4.1
4.9
5.9
4.6
5.2
4.1
5.3
5.1
4.7
4.7
6.9
5.2
wherein the binder polymer has a repeating unit selected from the following formulae:
Units U-4, U-8, U-25, U-30, U-32, U-36, U-42, U-55, U-56, U-59 to U-104, U-106 to U-109, U-115, U-118, U-121, U-123, U-127 to U-130, U-132 to U-134, V-2 to V-11, V-13 to V-17, V-20 to V-22, V-24 to V-26, V-30, V-33 to V-36, V-38, V-40 and V-43 to V-45:

51 more elements

wherein X and Y each independently represents —C(R5)(R6)—, —C(R5)═, —O—, —S—, —N(R)5— or —N═, Z1 represents O or S, Z2 represents O or a lone pair, Z3 represents —C(R5)(R6)—, C(R5)═, —O—, —S—, —N(R5)— or —N═, R1 to R6 each independently represents a substituent comprising at least one atom selected from hydrogen, carbon, oxygen, nitrogen, sulfur, phosphorus, halogen and silicon or appropriate two of R1 to R6 may be combined with each other to form a ring, provided that at least one of R1 to R6 represents a divalent connecting group comprising at least one atom selected from hydrogen, carbon, oxygen, nitrogen, sulfur, phosphorus, halogen and silicon and connecting to a skeleton of the binder polymer,
wherein the functional group having a dipole moment of 3.8 debye or more and being represented by the following formula (1), (2), (3), (4) or (5) is selected from the following groups:
Groups of Formula (2):
3.9
4.0
5.4
4.3
5.5
5.6
4.1
5.4
4.8
5.4
5.1
5.1
4.7
5.5
5.3
4.9
6.3
4.1
6.2
5.3
3.9
5.8
4.6
4.7
4.9
4.4
4.9
4.7
4.1
3.9
4.1
3.9
4.7
4.7
Grops of Formulae (3) to (5):
5.0
5.3
4.1
4.9
5.9
4.6
5.2
4.1
5.3
5.1
4.7
4.7
6.9
5.2
wherein the binder polymer is represented by one of the following structural formulae:
Binder polymers B-4, B-8, B-16, B-17, B-25, B-30 to B-32, B-36, B-42, B-55, B-56, B-59 to B-104, B-106, B-109, B-115, B-118, B-121 and B-123, B-127 to B-130, B-132 to B-134, B-136 to B-187 and B-190 to B-199, where the percentages of the constituent units are mole percentages:
Unit 1
Unit 2
Unit 3
Binder
Content
Content
Content
Polymer
No.
(%)
No.
(%)
No.
(%)
B-1
U-1
20
N-12
20
N-1
60
B-2
U-2
30
N-19
10
N-15
60
B-3
U-3
40
N-14
20
N-16
40
B-4
U-4
50
N-1
12
N-12
38
B-5
U-5
20
N-21
10
N-10
70
B-6
U-6
20
N-11
20
N-18
60
B-7
U-7
30
N-33
20
N-6
50
B-8
U-8
60
N-7
25
N-19
15
B-9
U-9
30
N-34
20
N-7
50
B-10
U-10
20
N-28
10
N-22
70
B-11
U-11
30
N-35
20
N-27
50
B-12
U-12
30
N-42
12
N-44
58
B-13
U-13
90
N-43
10
—
—
B-14
U-14
80
N-50
20
—
—
B-15
U-15
80
N-57
20
—
—
B-16
U-16
40
N-48
10
N-52
50
B-17
U-17
30
N-49
20
N-1
50
B-18
U-18
50
N-63
12
N-15
38
B-19
U-19
90
N-51
10
—
—
B-20
U-20
80
N-58
20
—
—
B-21
U-21
80
N-33
20
—
—
B-22
U-22
40
N-56
10
N-16
50
B-23
U-23
20
N-12
20
N-10
60
B-24
U-24
30
N-19
12
N-18
58
B-25
U-25
85
N-12
15
—
—
B-26
U-26
80
N-14
20
—
—
B-27
U-27
60
N-21
10
N-6
30
B-28
U-28
60
N-11
20
N-7
20
B-29
U-29
30
N-33
12
N-22
58
B-30
U-30
70
N-12
10
N-7
20
B-31
U-31
80
N-12
20
—
—
B-32
U-32
90
N-33
10
—
—
B-33
U-33
50
N-34
20
N-27
30
B-34
U-34
40
N-28
10
N-44
50
B-35
U-35
70
N-35
20
N-6
10
B-36
U-36
90
N-12
10
—
—
B-37
U-37
80
N-42
20
—
—
B-38
U-38
50
N-43
10
N-1
40
B-39
U-39
30
N-50
20
N-15
50
B-40
U-40
60
N-12
30
N-10
10
B-41
U-41
90
N-57
10
—
—
B-42
U-42
60
N-33
10
N-6
30
B-43
U-43
80
N-48
20
—
—
B-44
U-44
40
N-49
10
N-16
50
B-45
U-45
30
N-63
20
N-10
50
Unit 1
Unit 2
Unit 3
Binder
Content
Content
Content
Polymer
No.
(%)
No.
(%)
No.
(%)
B-46
U-46
30
N-51
12
N-18
58
B-47
U-47
90
N-58
10
—
—
B-48
U-48
80
N-56
20
—
—
B-49
U-49
80
N-12
20
—
—
B-50
U-50
90
N-19
10
—
—
B-51
U-51
30
N-14
20
N-6
50
B-52
U-52
40
N-21
12
N-7
48
B-53
U-53
40
N-11
10
N-22
50
B-54
U-54
80
N-33
20
—
—
B-55
U-55
70
N-35
10
N-6
20
B-56
U-56
30
N-34
12
N-27
58
B-57
U-57
60
N-28
10
N-44
30
B-58
U-58
50
N-35
20
N-52
30
B-59
U-59
60
N-42
10
N-6
30
B-60
U-60
80
N-42
20
—
—
B-61
U-61
90
N-43
10
—
—
B-62
U-62
80
N-50
20
—
—
B-63
U-63
88
N-14
12
—
—
B-64
U-64
88
N-57
12
—
—
B-65
U-65
50
N-48
10
N-1
40
B-66
U-66
30
N-49
20
N-15
50
B-67
U-67
50
N-63
10
N-16
40
B-68
U-68
80
N-51
20
—
—
B-69
U-69
70
N-43
10
N-28
20
B-70
U-70
80
N-58
20
—
—
B-71
U-71
30
N-56
10
N-10
60
B-72
U-72
60
N-12
20
N-18
20
B-73
U-73
50
N-19
12
N-6
38
B-74
U-74
30
N-14
10
N-7
60
B-75
U-75
30
N-21
20
N-22
50
B-76
U-76
30
N-11
20
N-27
50
B-77
U-77
90
N-33
10
—
—
B-78
U-78
60
N-34
20
N-44
20
B-79
U-79
50
N-28
12
N-52
38
B-80
U-80
60
N-35
10
N-1
30
B-81
U-81
80
N-42
20
—
—
B-82
U-82
80
N-43
20
—
—
B-83
U-83
90
N-50
10
—
—
B-84
U-84
70
N-33
30
—
—
B-85
U-85
30
N-57
12
N-15
58
B-86
U-86
30
N-48
10
N-16
60
B-87
U-87
80
N-49
20
—
—
B-88
U-88
80
N-63
20
—
—
Unit 1
Unit 2
Unit 3
Binder
Content
Content
Content
Polymer
No.
(%)
No.
(%)
No.
(%)
B-89
U-89
90
N-51
10
—
—
B-90
U-90
80
N-58
20
—
—
B-91
U-91
50
N-56
12
N-10
38
B-92
U-92
40
N-12
10
N-18
50
B-93
U-93
50
N-19
20
N-6
30
B-94
U-94
80
N-14
20
—
—
B-95
U-95
80
N-12
20
—
—
B-96
U-96
30
N-21
20
N-7
50
B-97
U-97
30
N-11
10
N-22
60
B-98
U-98
40
N-33
20
N-27
40
B-99
U-99
88
N-34
12
—
—
B-100
U-100
90
N-28
10
—
—
B-101
U-101
80
N-35
20
—
—
B-102
U-102
60
N-42
20
N-44
20
B-103
U-103
50
N-49
10
N-18
40
B-104
U-104
60
N-12
30
N-1
10
B-105
U-105
88
N-50
12
—
—
B-106
U-106
90
N-57
10
—
—
B-107
U-107
30
N-48
20
N-1
50
B-108
U-108
30
N-49
20
N-15
50
B-109
U-109
40
N-63
10
N-16
50
B-110
U-110
80
N-51
20
—
—
B-111
U-111
88
N-58
12
—
—
B-112
U-112
90
N-56
10
—
—
B-113
U-113
50
N-12
20
N-10
30
B-114
U-114
50
N-19
20
N-18
30
B-115
U-115
50
N-14
10
N-6
40
B-116
U-116
50
N-21
20
N-7
30
B-117
U-117
40
N-11
12
N-22
48
B-118
U-118
50
N-33
10
N-27
40
B-119
U-119
80
N-34
20
—
—
B-120
U-120
80
N-28
20
—
—
B-121
U-121
60
N-56
30
N-44
10
B-122
U-122
80
N-35
20
—
—
B-123
U-123
90
N-42
10
—
—
B-124
U-124
80
N-43
20
—
—
B-125
U-125
70
N-51
30
—
—
B-126
U-126
60
N-50
10
N-44
30
B-127
U-127
60
N-57
20
N-52
20
B-128
U-128
40
N-48
12
N-1
48
B-129
U-129
80
N-49
20
—
—
B-130
U-130
80
N-51
20
—
—
B-131
U-131
50
N-63
20
N-15
30
Binder
Unit 1
Unit 2
Unit 3
Polymer
No.
Content (%)
No.
No.
Content (%)
B-132
U-132
50
N-51
10
N-16
40
B-133
U-133
30
N-58
20
N-10
50
B-134
U-134
80
N-56
20
—
—
B-135
U-135
70
N-51
20
N-52
10
B-136
U-136
50
N-12
20
N-18
30
B-137
U-137
50
N-19
20
N-6
30
B-138.
U-138
50
N-14
20
N-7
30
B-139
U-139
50
N-21
20
N-22
30
B-140
U-140
50
N-11
20
N-27
30
B-141
U-141
50
N-33
20
N-44
30
B-142
U-142
50
N-34
20
N-52
30
B-143
U-143
50
N-28
20
N-1
30
B-144
U-144
50
N-58
20
N-44
30
B-145
U-145
50
N-35
20
N-15
30
B-146
U-146
50
N-42
20
N-16
30
B-147
U-147
50
N-43
20
N-10
30
B-148
U-148
50
N-50
20
N-18
30
B-149
U-149
60
N-51
20
N-52
20
B-150
U-150
70
N-51
20
N-44
10
Unit 1
Unit 2
Unit 3
Unit 4
Unit 5
Binder
Content
Content
Content
Content
Content
Polymer
No.
(%)
No.
(%)
No.
(%)
No.
(%)
No.
(%)
B-151
V-47
30
N-74
20
V-1
20
N-64
20
N-71
10
B-152
V-47
50
V-2
30
N-65
10
N-64
10
—
—
B-153
V-48
40
N-79
10
V-3
30
N-85
10
N-72
10
B-154
N-66
30
N-68
20
V-4
25
N-71
20
N-88
5
B-155
V-49
30
N-68
20
V-5
42
N-86
8
—
—
B-156
V-51
40
N-96
10
V-6
25
N-87
15
N-64
10
B-157
N-67
20
N-97
30
V-7
40
N-88
10
—
—
B-158
N-68
20
N-74
30
V-8
30
N-90
10
N-72
10
B-159
N-95
30
V-50
20
V-9
20
N-64
20
N-78
10
B-160
V-47
40
N-81
10
V-10
30
N-65
10
N-78
10
B-161
N-73
20
N-98
30
V-11
35
N-71
10
N-86
5
B-162
N-74
30
N-81
20
V-12
35
N-85
15
—
—
B-163
N-79
30
N-96
20
V-13
42
N-86
8
—
—
B-164
N-80
25
N-68
25
V-14
35
N-87
15
—
—
B-165
N-81
20
N-79
30
V-15
40
N-88
10
—
—
B-166
V-49
50
V-16
25
N-85
15
N-72
10
—
—
B-167
N-96
30
N-80
20
V-17
25
N-90
20
N-78
5
B-168
N-98
25
N-79
25
V-18
30
N-64
10
N-87
10
B-169
N-97
50
V-19
40
N-65
10
—
—
—
—
B-170
V-48
50
V-20
35
N-86
5
N-71
10
—
—
B-171
N-66
10
N-68
40
V-21
30
N-87
10
N-64
10
B-172
N-67
30
N-96
20
V-22
30
N-71
10
N-65
10
B-173
N-68
50
V-23
30
N-85
10
N-78
10
—
—
B-174
V-51
50
V-24
40
N-88
10
—
—
—
—
B-175
N-95
30
N-81
20
V-25
32
N-86
8
N-78
10
B-176
N-73
30
N-97
20
V-26
35
N-87
15
—
—
B-177
N-74
30
N-96
20
V-27
40
N-88
10
—
—
B-178
N-79
25
N-98
25
V-24
20
N-90
20
N-72
10
B-179
N-74
30
N-81
20
V-16
20
N-90
10
N-72
20
B-180
V-47
50
N-86
10
N-72
20
N-78
20
—
—
B-181
V-49
20
V-47
30
N-88
10
N-72
20
N-78
20
Unit 1
Unit 2
Unit 3
Unit 4
Unit 5
Binder
Content
Content
Content
Content
Content
Polymer
No.
(%)
No.
(%)
No.
(%)
No.
(%)
No.
(%)
B-182
V-51
25
V-48
25
V-2
30
N-90
10
N-72
10
B-183
V-47
50
N-75
15
V-29
30
N-69
5
—
—
B-184
V-48
40
N-96
10
N-82
20
V-30
30
—
—
B-185
N-74
20
N-97
30
N-75
15
V-31
35
—
—
B-186
N-95
20
N-68
30
N-82
20
V-32
20
N-69
10
B-187
N-73
10
N-79
40
N-75
15
V-33
25
N-69
10
B-188
V-49
50
N-82
20
V-34
30
—
—
—
—
B-189
N-67
20
N-81
30
N-75
10
V-35
20
N-69
20
B-190
V-51
50
N-82
30
V-36
20
—
—
—
—
B-191
N-98
50
N-75
15
V-37
20
N-69
15
—
—
B-192
N-79
30
N-98
20
N-82
20
V-38
20
N-69
10
B-193
N-74
30
N-81
20
N-82
20
V-34
15
V-36
15
B-194
V-51
25
V-48
25
N-75
20
N-69
30
—
—
B-195
V-39
30
N-76
20
N-85
10
N-72
20
N-78
20
B-196
V-40
50
V-2
20
N-90
10
V-16
20
—
—
B-197
V-41
30
V-44
20
V-16
25
N-85
15
N-72
10
B-198
V-42
30
N-83
20
V-24
40
N-88
10
—
—
B-199
V-43
30
N-76
20
N-75
20
N-69
30
—
—
B-200
V-44
30
V-39
20
N-82
20
V-34
15
V-36
15
B-201
V-45
20
N-83
30
N-82
20
V-30
30
—
—
B-202
V-46
20
N-83
30
N-75
20
N-69
30
—
—
B-203
N-83
20
N-76
30
V-2
20
N-90
10
V-16
20
B-204
N-83
30
N-76
20
N-82
20
V-34
15
V-36
15
B-205
V-52
20
N-70
30
N-88
10
N-72
20
N-78
20
B-206
V-53
40
N-77
10
N-85
10
V-2
40
—
—
B-207
N-70
20
N-77
30
N-85
10
V-2
40
—
—
B-208
V-52
25
V-53
25
V-2
25
V-16
25
—
—
wherein the structures of the U, V and N units of the binder polymer are as follows:

1,836 more elements

Dependencies are inferred from the claim text.

Facts

Application

11/964,125Filed 26 Dec 2007

Priority

JP P2006-35004726 Dec 2006

Published

US 2008/0199804 A121 Aug 2008

Granted

8 Jul 2014

Term ends

Not estimatedThe source records don’t support an estimate.

Classification23 codes

B41N 1/08
Metallic: for lithographic printing
B41C 1/1008
For lithographic printing; Master sheets for transferring a lithographic image to the forme: by removal or destruction of lithographic material on…
G03F 7/032
Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds: with binders
G03F 7/033
With binders: the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

Abstract

Claims15

Dependent claims

wherein the functional group having a dipole moment of 4.5 debye or more is selected from the following groups:

wherein X and Y each independently represents —C(R5)(R6)—, —C(R5)═, —O—, —S—, —N(R)5— or —N═, Z1 represents O or S, Z2 represents 0 or a lone pair, Z3 represents —C(R5)(R6)—, C(R5)═, —O—, —S—, —N(R5)— or —N═, R1 to R6 each independently represents a substituent comprising at least one atom selected from hydrogen, carbon, oxygen, nitrogen, sulfur, phosphorus, halogen and silicon or appropriate two of R1 to R6 may be combined with each other to form a ring, provided that at least one of R1 to R6 represents a divalent connecting group comprising at least one atom selected from hydrogen, carbon, oxygen, nitrogen, sulfur, phosphorus, halogen and silicon and connecting to a skeleton of the binder polymer,
wherein the functional group having a dipole moment of 3.8 debye or more and being represented by the formula (1), (2), (3), (4) or (5) is selected from the following groups:
Groups of Formula (2):
3.9
4.0
5.4
4.3
5.5
5.6
4.1
5.4
4.8
5.4
5.1
5.1
4.7
5.5
5.3
4.9
6.3
4.1
6.2
5.3
3.9
5.8
4.6
4.7
4.9
4.4
4.9
4.7
4.1
3.9
4.1
3.9
4.7
4.7
Grops of Formulae (3) to (5):
5.0
5.3
4.1
4.9
5.9
4.6
5.2
4.1
5.3
5.1
4.7
4.7
6.9
5.2
wherein the binder polymer has a repeating unit selected from the following formulae:
Units U-4, U-8, U-25, U-30, U-32, U-36, U-42, U-55, U-56, U-59 to U-104, U-106 to U-109, U-115, U-118, U-121, U-123, U-127 to U-130, U-132 to U-134, V-2 to V-11, V-13 to V-17, V-20 to V-22, V-24 to V-26, V-30, V-33 to V-36, V-38, V-40 and V-43 to V-45:

51 more elements

wherein X and Y each independently represents —C(R5)(R6)—, —C(R5)═, —O—, —S—, —N(R)5— or —N═, Z1 represents O or S, Z2 represents O or a lone pair, Z3 represents —C(R5)(R6)—, C(R5)═, —O—, —S—, —N(R5)— or —N═, R1 to R6 each independently represents a substituent comprising at least one atom selected from hydrogen, carbon, oxygen, nitrogen, sulfur, phosphorus, halogen and silicon or appropriate two of R1 to R6 may be combined with each other to form a ring, provided that at least one of R1 to R6 represents a divalent connecting group comprising at least one atom selected from hydrogen, carbon, oxygen, nitrogen, sulfur, phosphorus, halogen and silicon and connecting to a skeleton of the binder polymer,
wherein the functional group having a dipole moment of 3.8 debye or more and being represented by the following formula (1), (2), (3), (4) or (5) is selected from the following groups:
Groups of Formula (2):
3.9
4.0
5.4
4.3
5.5
5.6
4.1
5.4
4.8
5.4
5.1
5.1
4.7
5.5
5.3
4.9
6.3
4.1
6.2
5.3
3.9
5.8
4.6
4.7
4.9
4.4
4.9
4.7
4.1
3.9
4.1
3.9
4.7
4.7
Grops of Formulae (3) to (5):
5.0
5.3
4.1
4.9
5.9
4.6
5.2
4.1
5.3
5.1
4.7
4.7
6.9
5.2
wherein the binder polymer is represented by one of the following structural formulae:
Binder polymers B-4, B-8, B-16, B-17, B-25, B-30 to B-32, B-36, B-42, B-55, B-56, B-59 to B-104, B-106, B-109, B-115, B-118, B-121 and B-123, B-127 to B-130, B-132 to B-134, B-136 to B-187 and B-190 to B-199, where the percentages of the constituent units are mole percentages:
Unit 1
Unit 2
Unit 3
Binder
Content
Content
Content
Polymer
No.
(%)
No.
(%)
No.
(%)
B-1
U-1
20
N-12
20
N-1
60
B-2
U-2
30
N-19
10
N-15
60
B-3
U-3
40
N-14
20
N-16
40
B-4
U-4
50
N-1
12
N-12
38
B-5
U-5
20
N-21
10
N-10
70
B-6
U-6
20
N-11
20
N-18
60
B-7
U-7
30
N-33
20
N-6
50
B-8
U-8
60
N-7
25
N-19
15
B-9
U-9
30
N-34
20
N-7
50
B-10
U-10
20
N-28
10
N-22
70
B-11
U-11
30
N-35
20
N-27
50
B-12
U-12
30
N-42
12
N-44
58
B-13
U-13
90
N-43
10
—
—
B-14
U-14
80
N-50
20
—
—
B-15
U-15
80
N-57
20
—
—
B-16
U-16
40
N-48
10
N-52
50
B-17
U-17
30
N-49
20
N-1
50
B-18
U-18
50
N-63
12
N-15
38
B-19
U-19
90
N-51
10
—
—
B-20
U-20
80
N-58
20
—
—
B-21
U-21
80
N-33
20
—
—
B-22
U-22
40
N-56
10
N-16
50
B-23
U-23
20
N-12
20
N-10
60
B-24
U-24
30
N-19
12
N-18
58
B-25
U-25
85
N-12
15
—
—
B-26
U-26
80
N-14
20
—
—
B-27
U-27
60
N-21
10
N-6
30
B-28
U-28
60
N-11
20
N-7
20
B-29
U-29
30
N-33
12
N-22
58
B-30
U-30
70
N-12
10
N-7
20
B-31
U-31
80
N-12
20
—
—
B-32
U-32
90
N-33
10
—
—
B-33
U-33
50
N-34
20
N-27
30
B-34
U-34
40
N-28
10
N-44
50
B-35
U-35
70
N-35
20
N-6
10
B-36
U-36
90
N-12
10
—
—
B-37
U-37
80
N-42
20
—
—
B-38
U-38
50
N-43
10
N-1
40
B-39
U-39
30
N-50
20
N-15
50
B-40
U-40
60
N-12
30
N-10
10
B-41
U-41
90
N-57
10
—
—
B-42
U-42
60
N-33
10
N-6
30
B-43
U-43
80
N-48
20
—
—
B-44
U-44
40
N-49
10
N-16
50
B-45
U-45
30
N-63
20
N-10
50
Unit 1
Unit 2
Unit 3
Binder
Content
Content
Content
Polymer
No.
(%)
No.
(%)
No.
(%)
B-46
U-46
30
N-51
12
N-18
58
B-47
U-47
90
N-58
10
—
—
B-48
U-48
80
N-56
20
—
—
B-49
U-49
80
N-12
20
—
—
B-50
U-50
90
N-19
10
—
—
B-51
U-51
30
N-14
20
N-6
50
B-52
U-52
40
N-21
12
N-7
48
B-53
U-53
40
N-11
10
N-22
50
B-54
U-54
80
N-33
20
—
—
B-55
U-55
70
N-35
10
N-6
20
B-56
U-56
30
N-34
12
N-27
58
B-57
U-57
60
N-28
10
N-44
30
B-58
U-58
50
N-35
20
N-52
30
B-59
U-59
60
N-42
10
N-6
30
B-60
U-60
80
N-42
20
—
—
B-61
U-61
90
N-43
10
—
—
B-62
U-62
80
N-50
20
—
—
B-63
U-63
88
N-14
12
—
—
B-64
U-64
88
N-57
12
—
—
B-65
U-65
50
N-48
10
N-1
40
B-66
U-66
30
N-49
20
N-15
50
B-67
U-67
50
N-63
10
N-16
40
B-68
U-68
80
N-51
20
—
—
B-69
U-69
70
N-43
10
N-28
20
B-70
U-70
80
N-58
20
—
—
B-71
U-71
30
N-56
10
N-10
60
B-72
U-72
60
N-12
20
N-18
20
B-73
U-73
50
N-19
12
N-6
38
B-74
U-74
30
N-14
10
N-7
60
B-75
U-75
30
N-21
20
N-22
50
B-76
U-76
30
N-11
20
N-27
50
B-77
U-77
90
N-33
10
—
—
B-78
U-78
60
N-34
20
N-44
20
B-79
U-79
50
N-28
12
N-52
38
B-80
U-80
60
N-35
10
N-1
30
B-81
U-81
80
N-42
20
—
—
B-82
U-82
80
N-43
20
—
—
B-83
U-83
90
N-50
10
—
—
B-84
U-84
70
N-33
30
—
—
B-85
U-85
30
N-57
12
N-15
58
B-86
U-86
30
N-48
10
N-16
60
B-87
U-87
80
N-49
20
—
—
B-88
U-88
80
N-63
20
—
—
Unit 1
Unit 2
Unit 3
Binder
Content
Content
Content
Polymer
No.
(%)
No.
(%)
No.
(%)
B-89
U-89
90
N-51
10
—
—
B-90
U-90
80
N-58
20
—
—
B-91
U-91
50
N-56
12
N-10
38
B-92
U-92
40
N-12
10
N-18
50
B-93
U-93
50
N-19
20
N-6
30
B-94
U-94
80
N-14
20
—
—
B-95
U-95
80
N-12
20
—
—
B-96
U-96
30
N-21
20
N-7
50
B-97
U-97
30
N-11
10
N-22
60
B-98
U-98
40
N-33
20
N-27
40
B-99
U-99
88
N-34
12
—
—
B-100
U-100
90
N-28
10
—
—
B-101
U-101
80
N-35
20
—
—
B-102
U-102
60
N-42
20
N-44
20
B-103
U-103
50
N-49
10
N-18
40
B-104
U-104
60
N-12
30
N-1
10
B-105
U-105
88
N-50
12
—
—
B-106
U-106
90
N-57
10
—
—
B-107
U-107
30
N-48
20
N-1
50
B-108
U-108
30
N-49
20
N-15
50
B-109
U-109
40
N-63
10
N-16
50
B-110
U-110
80
N-51
20
—
—
B-111
U-111
88
N-58
12
—
—
B-112
U-112
90
N-56
10
—
—
B-113
U-113
50
N-12
20
N-10
30
B-114
U-114
50
N-19
20
N-18
30
B-115
U-115
50
N-14
10
N-6
40
B-116
U-116
50
N-21
20
N-7
30
B-117
U-117
40
N-11
12
N-22
48
B-118
U-118
50
N-33
10
N-27
40
B-119
U-119
80
N-34
20
—
—
B-120
U-120
80
N-28
20
—
—
B-121
U-121
60
N-56
30
N-44
10
B-122
U-122
80
N-35
20
—
—
B-123
U-123
90
N-42
10
—
—
B-124
U-124
80
N-43
20
—
—
B-125
U-125
70
N-51
30
—
—
B-126
U-126
60
N-50
10
N-44
30
B-127
U-127
60
N-57
20
N-52
20
B-128
U-128
40
N-48
12
N-1
48
B-129
U-129
80
N-49
20
—
—
B-130
U-130
80
N-51
20
—
—
B-131
U-131
50
N-63
20
N-15
30
Binder
Unit 1
Unit 2
Unit 3
Polymer
No.
Content (%)
No.
No.
Content (%)
B-132
U-132
50
N-51
10
N-16
40
B-133
U-133
30
N-58
20
N-10
50
B-134
U-134
80
N-56
20
—
—
B-135
U-135
70
N-51
20
N-52
10
B-136
U-136
50
N-12
20
N-18
30
B-137
U-137
50
N-19
20
N-6
30
B-138.
U-138
50
N-14
20
N-7
30
B-139
U-139
50
N-21
20
N-22
30
B-140
U-140
50
N-11
20
N-27
30
B-141
U-141
50
N-33
20
N-44
30
B-142
U-142
50
N-34
20
N-52
30
B-143
U-143
50
N-28
20
N-1
30
B-144
U-144
50
N-58
20
N-44
30
B-145
U-145
50
N-35
20
N-15
30
B-146
U-146
50
N-42
20
N-16
30
B-147
U-147
50
N-43
20
N-10
30
B-148
U-148
50
N-50
20
N-18
30
B-149
U-149
60
N-51
20
N-52
20
B-150
U-150
70
N-51
20
N-44
10
Unit 1
Unit 2
Unit 3
Unit 4
Unit 5
Binder
Content
Content
Content
Content
Content
Polymer
No.
(%)
No.
(%)
No.
(%)
No.
(%)
No.
(%)
B-151
V-47
30
N-74
20
V-1
20
N-64
20
N-71
10
B-152
V-47
50
V-2
30
N-65
10
N-64
10
—
—
B-153
V-48
40
N-79
10
V-3
30
N-85
10
N-72
10
B-154
N-66
30
N-68
20
V-4
25
N-71
20
N-88
5
B-155
V-49
30
N-68
20
V-5
42
N-86
8
—
—
B-156
V-51
40
N-96
10
V-6
25
N-87
15
N-64
10
B-157
N-67
20
N-97
30
V-7
40
N-88
10
—
—
B-158
N-68
20
N-74
30
V-8
30
N-90
10
N-72
10
B-159
N-95
30
V-50
20
V-9
20
N-64
20
N-78
10
B-160
V-47
40
N-81
10
V-10
30
N-65
10
N-78
10
B-161
N-73
20
N-98
30
V-11
35
N-71
10
N-86
5
B-162
N-74
30
N-81
20
V-12
35
N-85
15
—
—
B-163
N-79
30
N-96
20
V-13
42
N-86
8
—
—
B-164
N-80
25
N-68
25
V-14
35
N-87
15
—
—
B-165
N-81
20
N-79
30
V-15
40
N-88
10
—
—
B-166
V-49
50
V-16
25
N-85
15
N-72
10
—
—
B-167
N-96
30
N-80
20
V-17
25
N-90
20
N-78
5
B-168
N-98
25
N-79
25
V-18
30
N-64
10
N-87
10
B-169
N-97
50
V-19
40
N-65
10
—
—
—
—
B-170
V-48
50
V-20
35
N-86
5
N-71
10
—
—
B-171
N-66
10
N-68
40
V-21
30
N-87
10
N-64
10
B-172
N-67
30
N-96
20
V-22
30
N-71
10
N-65
10
B-173
N-68
50
V-23
30
N-85
10
N-78
10
—
—
B-174
V-51
50
V-24
40
N-88
10
—
—
—
—
B-175
N-95
30
N-81
20
V-25
32
N-86
8
N-78
10
B-176
N-73
30
N-97
20
V-26
35
N-87
15
—
—
B-177
N-74
30
N-96
20
V-27
40
N-88
10
—
—
B-178
N-79
25
N-98
25
V-24
20
N-90
20
N-72
10
B-179
N-74
30
N-81
20
V-16
20
N-90
10
N-72
20
B-180
V-47
50
N-86
10
N-72
20
N-78
20
—
—
B-181
V-49
20
V-47
30
N-88
10
N-72
20
N-78
20
Unit 1
Unit 2
Unit 3
Unit 4
Unit 5
Binder
Content
Content
Content
Content
Content
Polymer
No.
(%)
No.
(%)
No.
(%)
No.
(%)
No.
(%)
B-182
V-51
25
V-48
25
V-2
30
N-90
10
N-72
10
B-183
V-47
50
N-75
15
V-29
30
N-69
5
—
—
B-184
V-48
40
N-96
10
N-82
20
V-30
30
—
—
B-185
N-74
20
N-97
30
N-75
15
V-31
35
—
—
B-186
N-95
20
N-68
30
N-82
20
V-32
20
N-69
10
B-187
N-73
10
N-79
40
N-75
15
V-33
25
N-69
10
B-188
V-49
50
N-82
20
V-34
30
—
—
—
—
B-189
N-67
20
N-81
30
N-75
10
V-35
20
N-69
20
B-190
V-51
50
N-82
30
V-36
20
—
—
—
—
B-191
N-98
50
N-75
15
V-37
20
N-69
15
—
—
B-192
N-79
30
N-98
20
N-82
20
V-38
20
N-69
10
B-193
N-74
30
N-81
20
N-82
20
V-34
15
V-36
15
B-194
V-51
25
V-48
25
N-75
20
N-69
30
—
—
B-195
V-39
30
N-76
20
N-85
10
N-72
20
N-78
20
B-196
V-40
50
V-2
20
N-90
10
V-16
20
—
—
B-197
V-41
30
V-44
20
V-16
25
N-85
15
N-72
10
B-198
V-42
30
N-83
20
V-24
40
N-88
10
—
—
B-199
V-43
30
N-76
20
N-75
20
N-69
30
—
—
B-200
V-44
30
V-39
20
N-82
20
V-34
15
V-36
15
B-201
V-45
20
N-83
30
N-82
20
V-30
30
—
—
B-202
V-46
20
N-83
30
N-75
20
N-69
30
—
—
B-203
N-83
20
N-76
30
V-2
20
N-90
10
V-16
20
B-204
N-83
30
N-76
20
N-82
20
V-34
15
V-36
15
B-205
V-52
20
N-70
30
N-88
10
N-72
20
N-78
20
B-206
V-53
40
N-77
10
N-85
10
V-2
40
—
—
B-207
N-70
20
N-77
30
N-85
10
V-2
40
—
—
B-208
V-52
25
V-53
25
V-2
25
V-16
25
—
—
wherein the structures of the U, V and N units of the binder polymer are as follows:

1,836 more elements

Dependencies are inferred from the claim text.

Facts

Application

11/964,125Filed 26 Dec 2007

Priority

JP P2006-35004726 Dec 2006

Published

US 2008/0199804 A121 Aug 2008

Granted

8 Jul 2014

Term ends

Not estimatedThe source records don’t support an estimate.

Classification23 codes

B41N 1/08
Metallic: for lithographic printing
B41C 1/1008
For lithographic printing; Master sheets for transferring a lithographic image to the forme: by removal or destruction of lithographic material on…
G03F 7/032
Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds: with binders
G03F 7/033
With binders: the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

Polymerizable composition, lithographic printing plate precursor and lithographic printing method

Life of this patent

Abstract

Claims15

Polymerizable composition, lithographic printing plate precursor and lithographic printing method

Life of this patent

Abstract

Claims15