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US 8,540,885 B2Granted
Use of alkoxylated polyalkanolamines for splitting oil-water emulsions
AssigneeBASF SE
InventorsSophia Ebert, Andreas Eichhorn
Life of this patent
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Abstract
The use of alkoxylated polyalkanolamines as demulsifiers for splitting oil-water emulsions, especially for splitting crude oil emulsions.
Claims20
A method of splitting oil-water emulsions, comprising adding polyalkanolamines to an oil-water emulsion, wherein polyalkanolamines are alkoxylated polyalkanolamines (III) which are obtained by the following process:
- (A) condensing at least one trialkanolamine of the general formula N(R1—OH)3 (Ia) and/or at least one dialkanolamine of the general formula R2—N(R1—OH)2 (Ib) to give a polyalkanolamine (II),
- where
- the R1 radicals are each independently a divalent, linear or branched aliphatic hydrocarbon radical having from 2 to 6 carbon atoms,
- the R2 radicals are each hydrogen and/or linear or branched aliphatic, cycloaliphatic and/or aromatic hydrocarbon radicals having from 1 to 30 carbon atoms, and
- the resulting polyalkanolamines (II) have a mean molar mass of from 1000 g/mol to 20 000 g/mol,
- (B) alkoxylating the resulting polyalkanolamine (II) with ethylene oxide and propylene oxide to form alkoxylated polyalkanolamines (III) which contains polyoxyalkylene groups, where
- the polyoxyalkylene groups formed have block structure of the general formula —(CH2CH2O)x(CH2CH(CH3)O)yH, and where x and y are each from 3 to 100, and
- the y/x ratio is >1.
5 more elements
Dependencies are inferred from the claim text.