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US 8,147,908 B2Granted
Increased throughput for large-scale production of low melt organoamine stabilized silver nano-particles
AssigneeXerox Corporation
InventorsMahya Mokhtari, Roger E. Gaynor, Marko D. Saban
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Abstract
Process for producing organoamine-stabilized silver nanoparticles with a molar ratio of silver salt to organoamine of about 1:4 to about 1:10 are disclosed. The process includes: forming a solution including an organic solvent and a first amount of organoamine; adding silver salt particles to the solution; adding a second amount of organoamine to the solution; adding a hydrazine to the solution; and reacting the solution to form an organoamine-stabilized silver nanoparticles.
Claims19
A method of producing organoamine-stabilized silver nanoparticles, comprising:
- forming a solution comprising an organic solvent and a first amount of organoamine and heating the solution to a first temperature;
- wherein the first temperature is from about 50° C. to about 80° C.;
- adding a silver salt to the solution heated to the first temperature;
- adding a second amount of organoamine to the solution heated to the first temperature;
- cooling the solution from the first temperature to a second temperature;
- adding a hydrazine to the solution to reduce the silver salt forming a reduced silver salt, and reacting the reduced silver salt with the organoamine to form organoamine-stabilized silver nanoparticles while maintaining the solution at the second temperature;
- and
- precipitating the solution after performing the reaction and recovering the organoamine-stabilized silver nanoparticles, by a two-solvent precipitation procedure comprising adding a non-solvent to the solution and then after the non-solvent is added, adding an alcohol to the solution;
- wherein the molar ratio of silver salt to total organoamine is from about 1:4 to about 1:10.
6 more elements
Dependencies are inferred from the claim text.