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US 7,745,653 B2Granted
Fluorochemical compounds having pendent silyl groups
Assignee3M Innovative Properties Company
InventorsSuresh Iyer, Thomas P. Klun, Oscar S. Benz, Wayne W. Fan
Life of this patent
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Abstract
Fluorochemical silane compounds and coating compositions derived therefrom are described. The compounds and compositions may be used in treating substrates, in particular substrates having a hard surface such as ceramics or glass, to render them water, oil, stain, and soil repellent.
Claims21
A compound of the formula
- wherein
- Rf is a fluorine-containing group of the formula:
- wherein
- Rf 1 is a monovalent perfluorooxyalkyl group, or a divalent a perfluorooxyalkylene group comprising one or more perfluorinated repeating units selected from the group consisting of —(CnF2nO)—, —(CF(Z)O)—, —(CF(Z)CnF2nO)—, —(CnF2nCF(Z)O)—, —(CF2CF(Z)O)—, and combinations thereof, wherein n is 1 to 4 and Z is a perfluoroalkyl group, a perfluoroalkoxy group, or perfluorooxyalkyl group,
- Q is a covalent bond, or a divalent alkylene or arylene group, said alkylene optionally containing one or more catenary heteroatoms,
- X2 is —O—, —NR4— or —S—, where R4 is H or C1-C4 alkyl,
- z is 1 or 2, and
- v is 0 or 1;
- Rl is a covalent bond, a polyvalent alkylene or arylene group, or combinations thereof, said alkylene groups optionally containing one or more catenary oxygen or nitrogen atoms:
- R2 is of the formula:
- wherein
- X2 is —O, —S—or —NR4—, where R4 is H or C1-C4 alkyl,
- R5 is C1-C4 alkyl, or —R6—Si(Yp)(R7)3-p or (Rf)x—R1—X2—C(O)—CH2CH2—;
- R6 is a divalent alkylene group, said alkylene groups optionally containing one or more catenary oxygen atoms;
- Y is a hydrolysable group,
- R7 is a monovalent alkyl or aryl group,
- p is 1, 2 or 3, and
- x and y are each independently at least 1, and z is 1 or 2.
15 more elements
Dependencies are inferred from the claim text.