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US 7,612,217 B2Granted
Sulfonium compound
AssigneeSumitomo Chemical Company, Limited
InventorsHiromu Sakamoto, Yukako Harada
Life of this patent
Estimating the term…
Abstract
The present invention provides a sulfonium compound represented by the formula (I): wherein Q1 and Q2 each independently represent a fluorine atom or a C1-C6 perfluoroalkyl group, and A+ represents an organic counter ion.
Claims5
A sulfonium compound represented by the formula (I):
- wherein Q1 and Q2 each independently represent a fluorine atom or a C1-C6 perfluoroalkyl group, and A+ represents an organic counter ion;
- wherein the organic counter ion is at least one cation selected from a cation represented by the formula (IIa):
- wherein P1, P2 and P3 each independently represent a C1-C30 alkyl group which may be substituted with at least one selected from a hydroxyl group, a C3-C12 cyclic hydrocarbon group and a C1-C12 alkoxy group, or a C3-C30 cyclic hydrocarbon group which may be substituted with at least one selected from a hydroxyl group and a C1-C12 alkoxy group, a cation represented by the formula (IIb):
- wherein P4 and P5 each independently represent a hydrogen atom, a hydroxyl group, a C1-C12 alkyl group or a C1-C12 alkoxy group, a cation represented by the formula (IIc):
- wherein P6 and P7 each independently represent a C1-C12 alkyl group or a C3-C12 cycloalkyl group, or P6 and P7 are bonded together to form a C3-C12 divalent acyclic hydrocarbon group which forms a ring together with the adjacent S+, and at least one —CH2— in the divalent acyclic hydrocarbon group may be replaced with —CO—, —O— or —S—, P8 represents a hydrogen atom, P9 represents a C1-C12 alkyl group, a C3-C12 cycloalkyl group or an aromatic group which may be substituted, or P8 and P9 are bonded together to form a divalent acyclic hydrocarbon group which forms a 2-oxocycloalkyl group together with the adjacent —CHCO—, and at least one —CH2— in the divalent acyclic hydrocarbon group may be replaced with —CO—, —O— or —S—, and a cation represented by the formula (IId):
- wherein P10, P11, P12, P13, P14, P15, P16, P17, P18, P19,P20and P21each independently represent a hydrogen atom, a hydroxyl group, a C1-C12 alkyl group or a C1-C12 alkoxy group, B represents a sulfur or oxygen atom and k represents 0 or 1.
3 more elements
A sulfonium compound represented by the formula (I):
- wherein Q1 and Q2 each independently represent a fluorine atom or a C1-C6 perfluoroalkyl group, and A+ represents an organic counter ion;
- wherein the organic counter ion is a cation represented by the formula (IIIa), (IIIb) or (IIIc):
- wherein P22, P23 and P24 each independently represent a C1-C20 alkyl group or a C3-C30 cyclic hydrocarbon group except a phenyl group, wherein at least one hydrogen atom in the C1-C20 alkyl group may be substituted with a hydroxyl group, a C1-C12 alkoxy group or a C3-C12 cyclic hydrocarbon group and wherein at least one hydrogen atom in the C3-C30 cyclic hydrocarbon group may be substituted with a hydroxyl group, a C1-C12 alkyl group or a C1-C12 alkoxy group, and P25, P26, P27, P28, P29 and P30 each independently represent a hydroxyl group, a C1-C12 alkyl group, a C1-C12 alkoxy group or a C3-C12 cyclic hydrocarbon group, and l, m, n, p, q and r each independently represent an integer of 0 to 5.
A sulfonium compound represented by the formula (I):
- wherein Q1 and Q2 each independently represent a fluorine atom or a C1-C6 perfluoroalkyl group, and A+ represents an organic counter ion;
- wherein the organic counter ion is a cation represented by the formula (IIIa):
- wherein P25, P26, and P27 each independently represent a hydroxyl group, a C1-C12 alkyl group, a C1-C12 alkoxy group, or a C3-12 cyclic hydrocarbon group, and l, m and n each independently represent an integer of 0 to 5.
A sulfonium compound represented by the formula (IV):
- wherein P25, P26, and P27 each independently represent a hydroxyl group, a C1-C12 alkyl group, a C1-C12 alkoxy group, or a C3-C12 cyclic hydrocarbon group, and l, m and n each independently represent an integer of 0 to 5.
A process for production of a sulfonate compound represented by the formula (VIII):
- wherein Q1 and Q2 each independently represent a fluorine atom or a C1-C6 perfluoroalkyl group, A+ represents an organic counter ion, and X represents a C1-C30 hydrocarbon group which may be substituted, which comprises reacting a sulfonium compound represented by the formula (I):
- wherein Q1, Q2 and A+ are the same as defined above, with a compound represented by the formula (VII):
- HO—X (VII)
- wherein X is the same as defined above.
1 more element
Dependencies are inferred from the claim text.