Catalyst composition for producing polyethylene terephthalate from terephthalic acid and ethylene glycol, and process therefore
AssigneeSaudi Basic Industries Corporation
InventorsZahir Bashir, Jamil Siddiqui, Venkatanathan Sampath, Khalid Al-Luhaidan
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Abstract
The present invention relates to a catalyst composition for producing polyethylene terephthalate from terephthalic acid and ethylene glycol, comprising: (i) an antimony compound, being present such that the elemental antimony is in a range of about 15 ppm to less than 150 ppm; (ii) a zinc compound, being present such that the elemental zinc is in a range of about 40 to about 160 ppm; as well as a process for the preparation thereof.
Claims15
Process for the production of polyethylene terephthalate from terephthalic acid and ethylene glycol, comprising the steps of:
- (a) preparing a catalyst composition consisting of an antimony compound, being present such that the elemental antimony content is in a range of about 100 to about 140 ppm, and a zinc compound, being present such that the elemental zinc content is in a range of about 80 to about 140 ppm, wherein the ppm amounts by weight are based on the theoretical yield of polyethylene terephthalate;
- (b) placing the catalyst composition, the terephthalic acid and the ethylene glycol in a vessel;
- and
- (c) reacting the terephthalic acid and the ethylene glycol in an esterification step and a polycondensation step to obtain polyethylene terephthalate.
Dependencies are inferred from the claim text.