Process for preparing equilibration products of organosiloxanes, the organopolysiloxanes thus obtainable, and use thereof

A process for preparing SiH-functional organosiloxane equilibration products by rearrangement of the siloxane bond over a sulfonic-acid cation exchange resin, an organosiloxane or organosiloxane mixture utilized as starting material being contacted at a temperature of 10° C. to 120° C. with a macrocrosslinked cation exchange resin containing sulfonic acid groups, and the equilibrated organosiloxanes obtained being isolated, which comprises using a cation exchange resin for which the product P of its specific surface area and its average pore diameter is P<2.2×10−3 m3/kg and the specific surface area A is <35 m2/g.