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US 7,465,688 B2Granted
Process for the isomerization of metallocene compounds
AssigneeBasell Polyolefine GmbH
InventorsSimona Guidotti, Davide Balboni
Life of this patent
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Abstract
An isomerization process comprising the step of contacting a slurry or a solution comprising the meso or meso-like form of one or more bridged metallocene compounds of group 4 of the Periodic Table of the Elements having C2 or C2-like symmetry with an isomerization catalyst of formula (I) [R4W]+X− (I) wherein: W is a nitrogen or a phosphorus atom; R, equal to or different from each other, are C1-C40 hydrocarbon radicals and X− is an halide atom.
Claims13
An isomerization process comprising:
- contacting a slurry or a solution comprising a meso or meso-like form of at least one bridged metallocene compound of group 4 of the Periodic Table of the Elements having C2 or C2-like symmetry with an isomerization catalyst of formula (I):
- [R4W]+X− (I)
- wherein W is nitrogen or phosphorus;
- R, equal to or different from each other, are C1-C40 hydrocarbon radicals optionally containing one or more heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements;
- two R can optionally join to form a saturated or unsaturated C5-C6 membered cycle containing W or two R can optionally join to form a radical of formula (II):
- wherein R1, equal to or different from each other, are C1-C20 hydrocarbon radicals optionally containing one or more heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements;
- P is phosphorous bonded with a double bond to W;
- and
- X− is a halide.
6 more elements
Dependencies are inferred from the claim text.