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AssigneesBASF SE, The Regents of the University of Michigan
InventorsUlrich Mueller, Gerald Lippert, Olga Schubert, Michael Hesse, Reinhard Hess, Michael Stoesser, Omar M. Yaghi
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A process for preparing an organometallic framework material comprising reacting at least one metal salt with at least one at least bidentate compound capable of coordination to the metal ion of said metal salt, in the presence of an aqueous solvent system and at least one base wherein at least one bidentate compound comprises at least carboxy group and at least one further group which is not a carboxy group and which is capable of forming a hydrogen bridge linkage.
A process for preparing an organometallic framework material comprising reacting at least one metal salt with at least one at least bidentate compound capable of coordinating to the metal ion of said metal salt, in the presence of an aqueous solvent system and at least one base wherein at least one bidentate compound comprises at least two carboxy groups and at least one hydroxy group which is capable of forming a hydrogen bridge linkage.
A process for preparing an organometallic framework material comprising reacting at least one metal salt with at least one at least bidentate compound capable of co-ordination to the metal ion of said metal salt, in the presence of an aqueous solvent and at least one alkali metal hydroxide or alkaline earth metal hydroxide wherein the at least one bidentate compound comprises two hydroxy groups and two carboxy groups.
A process for preparing an organometallic framework material comprising reacting a zinc salt with a bidentate compound in the presence of an aqueous solvent and sodium hydroxide wherein the bidentate compound is dihydroxy terephthalic acid.
A process for preparing an organometallic framework material comprising reacting a zinc salt with dihydroxy terephthalic acid in the presence of water as solvent and sodium hydroxide wherein the reaction is carried out at a pH in the range of from 7.3 to 7.6.
A method of using an organometallic framework material, comprising at least one metal ion and at least one at least bidentate organic compound coordinately bound to said at least one metal ion, said organometallic framework material being obtainable by a process comprising reacting at least one metal salt with at least one at least bidentate compound capable of coordination to the metal ion of said metal salt, in the presence of an aqueous solvent system and at least one base wherein at least one bidentate compound comprises at least carboxy group and at least one hydroxy group comprising the step of catalyzing, adsorbing, desiccating, flame retarding, storing or depositing active substances, sensor material, pigment, or electronic component.
A method of catalyzing a reaction of an organic compound comprising the step of reacting an organic compound catalyzed by a catalyst wherein the catalyst is an organometallic framework material comprising at least one metal ion and at least one at least bidentate organic compound coordinately bound to said at least one metal ion, obtainable by a process comprising reacting at least one metal salt with at least one at least bidentate compound capable of coordination to the metal ion of said metal salt, in the presence of an aqueous solvent system and at least one base wherein at least one bidentate compound comprises at least carboxy group and at least one hydroxy group.
Dependencies are inferred from the claim text.