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US 7,408,081 B2Granted
Process for treating an aqueous medium containing cyclohexanone oxime and cyclohexanone
AssigneeDsm IP Assets B.V.
InventorsArno Benneker, Henk Oevering, Johannes A. L. Brouwers
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Abstract
The invention relates to a process for treating an aqueous medium containing cyclohexanone oxime and cyclohexanone, said process comprising stripping the aqueous medium with steam, wherein said stripping is carried out at a pressure higher than 0.11 MPa. The invention also relates to a process for the preparation of cyclohexanone oxime, which involves stripping at a pressure higher than 0.11 MPa.
Claims17
A process for preparing cyclohexanone oxime comprising:
- passing an aqueous medium containing phosphate from a hydroxylammonium synthesis zone to a cyclohexanone oxime synthesis zone, from the cyclohexanone oxime synthesis zone to a stripping zone and from the stripping zone back to the hydroxylammonium synthesis zone,
- in said hydroxylammonium synthesis zone, preparing hydroxylammonium by catalytically reducing nitrate or nitrogen oxide with hydrogen;
- in said cyclohexanone oxime synthesis zone, preparing cyclohexanone oxime by reacting hydroxylammonium with cyclohexanone;
- in said stripping zone, stripping the aqueous medium with steam;
- wherein said stripping is carried out at a pressure higher than 0.11 MPa.
2 more elements
Dependencies are inferred from the claim text.