Nitrogen-doped silicon substantially free of oxidation induced stacking faults
AssigneeMEMC Electronic Materials, Inc.
InventorsHiroyo Haga, Takaaki Aoshima, Mohsen Banan
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Abstract
The present invention relates to a process for forming single crystal silicon ingots or wafers that contain an axially symmetric region in which vacancies are the predominant intrinsic point defect, that are substantially free of oxidation induced stacking faults, and are nitrogen doped to stabilize oxygen precipitation nuclei therein.
Claims18
A process for growing a single crystal silicon ingot in which the ingot comprises a central axis, a seed end, an opposite end and a constant diameter portion between the seed end and the opposite end having a lateral surface, a radius, R, extending from the central axis to the lateral surface and a nominal diameter of about D mm, the ingot being grown from a silicon melt in a crucible and then cooled from the solidification temperature in accordance with the Czochralski method, the process comprising:
- growing the constant diameter portion of the crystal at a rate, v, to cause the formation of an axially symmetrical region in which vacancies are the predominant intrinsic point defect, the axially symmetric region being generally cylindrical in shape and having a radius, ras, extending from the central axis wherein ras is at least about 0.95 R and a length as measured along the central axis of at least about 20% of the length of the constant diameter portion of the ingot;
- rotating the crucible and the ingot in opposite directions during the formation of the axially symmetric region at rates Rmelt and Ringot, respectively, to incorporate between about 7 ppma and about 10.5 ppma of oxygen at about 5-6 mm inward of the lateral surface;
- and
- doping the silicon melt with nitrogen so that about 1×1013 nitrogen atoms/cm3 to about 1×1015 nitrogen atoms/cm3 are incorporated into the ingot during the formation of the axially symmetric region.
Dependencies are inferred from the claim text.