A silver halide emulsion comprising an oxidatively dimerized form of a mesoionic compound having a thiolate structure, and silver chloride of at least 90 mol % by content, the oxidatively dimerized form of a mesoionic compound having a thiolate structure represented by the following formula:
- wherein in the formula, f represents a sulfur atom, e represents a carbon atom, and a, b, c, and d are each an unsubstituted or substituted atom constituting an aromatic 5-membered heterocycle having a positive charge and each independently represents a C—R group, an N—R′ group, an oxygen atom, or a sulfur atom, where R and R′ each independently represents a hydrogen atom or a substituent.