Method of producing a photographic copolymer coupler
AssigneeFuji Photo Film Co., Ltd.
InventorHaruyoshi Goto
Life of this patent
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Abstract
There is disclosed a method of producing a copolymer by polymerizing at least two monomers having different reactivity as constitutional components, comprising carrying out a polymerization while adding a monomer component B having high reactivity, to a solution of a monomer component A having low reactivity dissolved in a non-aqueous solvent having a boiling point of 55° C. to 120° C., in the presence of a polymerization initiator. The method can give a copolymer high in solubility and suitable for the processing by the flush vacuum dry system, and the method is excellent from the standpoint of the production capacity and stable/safe production throughout the process.
Claims20
A method of producing a photographic copolymer coupler composed of at least three monomers having different reactivity as constitutional components:
- a monomer component A, a monomer component B and a monomer components C, comprising carrying out a polymerization while adding, dropwise,
- a solution of the monomer component B having higher reactivity than the monomer component A, dissolved in a non-aqueous solvent having a boiling point of 55° C. to 120° C. and a solution of monomer component C,
- to a solution of the monomer component A dissolved in a non-aqueous solvent having a boiling point of 55° C. to 120° C., in the presence of a polymerization initiator,
- wherein the said monomer components A and C are non-color-forming components and said monomer component B is a coupler component.
A method of producing a photographic copolymer coupler having at least two monomers as constitutional components:
- a monomer component A and a monomer component B, comprising carrying out a polymerization while adding, dropwise, a solution of the monomer component B dissolved in a non-aqueous solvent having a boiling point of 55° C. to 120° C., to a solution of the monomer component A dissolved in a non-aqueous solvent having a boiling point of 55° C. to 120° C., in the presence of a polymerization initiator,
- wherein the said monomer component B is a monomer coupler represented by the following formula (I), (II), or (III):
- wherein R represents a hydrogen atom, a lower alkyl group having 1 to 4 carbon atoms, or a chlorine atom;
- X represents —CONH—, —NH—, —NHCONH—, or —NHCOO—;
- Y represents —CONH— or —COO—;
- A represents an unsubstituted or substituted straight-chain or branched alkylene group, or an unsubstituted or substituted phenylene group;
- Ar represents an unsubstituted or substituted phenyl group;
- Za, Zb, Zc, and Zd each represent methine, substituted methine, or —N═;
- and m and n are each 0 or 1;
- wherein R1 represents a hydrogen atom, a chlorine atom, an alkyl group, or aryl group;
- L1 represents —C(═O)N(R2)—, —C(═O)O—, —N(R2)C)═O)—, —OC(═O)—, formula (IV), formula (V), or formula (VI), shown below, in which R2 represents a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group;
- L2 represents a divalent linking group to link L1 and Q1, i is 0 or 1, j is 0 or 1, and Q1 represents a yellow coupler residue capable of forming a yellow dye upon coupling with an oxidation product of an aromatic primary amine developing agent;
- wherein R3 has the same meaning as R1, L3 has the same meaning as L1, L4 has the same meaning as L2, g has the same meaning as i, h has the same meaning as j, and Q2 represents a cyan coupler residue capable of forming a cyan dye upon coupling with an oxidation product of an aromatic primary amine developing agent;
- wherein R4 represents a substituent, R5 has the same meaning as R2, and k represents an integer of 0 to 4,
- wherein the said monomer component A is a non-color-forming monomer.
A silver halide photographic light-sensitive material, which contains a copolymer produced by a production method of a copolymer by polymerizing at least two monomers having different reactivity as constitutional components, wherein the production method comprises carrying out a polymerization while adding a monomer component B having high reactivity, to a solution of a monomer component A having low reactivity dissolved in a non-aqueous solvent having a boiling point of 55° C. to 120° C., in the presence of a polymerization initiator.
The silver halide photographic light-sensitive material as claimed in 6, wherein the copolymer is a polymer coupler.
Dependencies are inferred from the claim text.