Positive photoresist composition comprising a phenolic compound having both an acid-decomposable group and a naphthoquinonediazide sulfonyl group
AssigneeTokyo Ohka Kogyo Co., Ltd.
InventorsKousuke Doi, Ken Miyagi, Atsuko Hirata, Hidekatsu Kohara, Toshimasa Nakayama
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Abstract
A positive photoresist composition includes (A) an alkali-soluble resin, in which part of phenolic hydroxyl groups is protected by an acid-decomposable group; (B) a quinonediazide ester; and (C) a compound which generates an acid upon irradiation of light with a wavelength of 365 nm. This positive photoresist composition can form a fine pattern of about 0.35 μm in the photolithographic process using i-ray (365 nm), is excellent in focal depth range properties in such an ultrafine region, and has a high sensitivity.
Claims8
A positive photoresist composition comprising:
- (A) an alkali-soluble resin;
- (B) a quinonediazide ester represented by the following Formula (I):
- wherein each of R1, R2, R3, R4, R5, R6, R7 and R8 is independently a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or a cycloalkyl group;
- each of R9, R10 and R11 is independently a hydrogen atom or an alkyl group having 1 to 6 carbon atoms;
- Q is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, or Q is combined with R9 to form a cyclic ring having 3 to 6 carbon atom members, or a residue represented by the following Formula (II):
- wherein each of R12 and R13 is independently a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or a cycloalkyl group;
- and c denotes an integer of 1 to 3;
- each of D is independently a hydrogen atom, a 1,2-naphthoquinonediazidosulfonyl group, or an acid-decomposable group, where at least one of D is a 1,2-naphthoquinonediazidosulfonyl group and at least one of D is an acid-decomposable group;
- each of a and b independently denotes an integer of 1 to 3;
- d denotes an integer of 0 to 3;
- and n denotes an integer of 0 to 3;
- and
- (C) a compound which generates an acid upon irradiation of light with a wavelength of 365 nm.
Dependencies are inferred from the claim text.