Light-sensitive silver halide photographic film material and radiographic intensifying screen-film combination
AssigneeAgfa-Gevaert
InventorsAnn Verbeeck, Paul Callant, Freddy Henderickx
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AssigneeAgfa-Gevaert
InventorsAnn Verbeeck, Paul Callant, Freddy Henderickx
Estimating the term…
A light-sensitive silver halide photographic film material has been provided, said film material comprising a transparent support and on both sides thereof at least one light-sensitive emulsion layer having spectrally and chemically sensitized tabular silver halide grains rich in silver bromide, further having silver iodide in an amount of less than 3 mole % based on silver, with two flat parallel {111} crystal faces, said grains accounting for a total projective surface of said parallel crystal faces in said emulsion of at least 50%, further having an average aspect ratio of at least 2:1, a grain thickness of from 0.05 up to 0.15 μm, a site-directing azacyanine compound satisfying the general formulae disclosed herein in an amount of not less than 1×10−4 mole per mole of silver halide coated and one or more J-aggregating spectrally sensitizing dye(s), wherein a molar ratio amount between said site directing compound and said J-aggregating spectrally sensitizing dye(s) is at least 1:6 for a grain coverage of said {111} tabular grains exceeding 50%. A radiographic screen/film combination has also been described comprising said light-sensitive silver halide photographic film material and two supporting or self-supporting X-ray intensifying screens) comprising luminescent phosphors, wherein by contacting the film material with a sandwich of a pair of said intensifying screens and exposing said combination to X-rays, emission of radiation by said luminescent phosphors in the wavelength range for which said material has been made spectrally sensitive provides a black-and-white diagnostic image after processing of said exposed radiographic film material.
Light-sensitive silver halide photographic film material comprising a transparent support and on one or both sides thereof at least one light-sensitive emulsion layer having spectrally and chemically sensitized tabular silver halide grains rich in silver bromide, wherein said grains rich in silver bromide have iodide in an amount of from 0.1 mole % up to 0.4 mole %, based on silver, with two flat parallel {111} crystal faces, said grains accounting for a total projective surface of said parallel crystal faces in said emulsion of at least 50%, further having an average aspect ratio of at least 2:1, a grain thickness of from 0.05 up to 0.15 μm, a site-directing compound satisfying general formula (I.1) or (I.2) in an amount of not less than 1×10−4 mole per mole of silver coated and one or more J-aggregating spectrally sensitizing dye(s), wherein a molar ratio amount between said site directing compound and said J-aggregating spectrally sensitizing dye(s) is at least 1:6 for a grain coverage of said {111} tabular grains exceeding 50% and wherein said site-directing compounds are represented by the formula (I.1) or (I.2)
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