Polishes comprising aminoorganopolysiloxanes containing fluoro groups

A polish for surfaces, comprising at least one aminoorganopolysiloxane (A) which is solid at room temperature, contains fluoro groups is able to change its aggregate state reversibly as a result of changes in temperature wherein said aminoorganopolysiloxane (A) comprises units of the general formula I

• AaRbSiXcO(4-a-b-c)/2 (I),
• where
• R are independently monovalent, optionally substituted hydrocarbon radicals having 1 to 40 carbon atoms,
• X are independently chlorine or a radical of the formula —OR1 where R1 is hydrogen or an alkyl radical having 1 to 8 carbon atoms, optionally substituted by ether oxygen atoms, or X is a radical of the general formula II
• —R2{[CH(CH3)CH2O]e[CH2CH2O]f[(CH2)4O]gR3}y−1 (II),
• where
• R2 is a divalent, trivalent or tetravalent hydrocarbon radical having 2 to 30 carbon atoms optionally interrupted by oxygen atoms and substituted by one or more groups of the formulae
• —C(O)—O—, —C(O)—NR3—, —SO2—NR3—, —NR3—, —N═ and —S—
• y in accordance with the valence of radical R2 is 2, 3 or 4,
• R3 is hydrogen or a hydrocarbon radical which has 1 to 40 carbon atoms and is optionally substituted by a group —C(O), and
• e, f and g independently of one another, are 0 or an integer from 1 to 200, with the proviso that the sum e+f+g is ≧1,
• A is a radical of the general formula III
• —R4{—CnF2n+1}y−1 (III),
• where
• R4 has the same definition as R2,
• y in accordance with the valency of radical R4 is 2, 3 or 4 and n is a number from 1 to 40,
• a is 0, 1 or 2,
• b is 0, 1, 2 or 3, and
• c is 0, 1, 2 or 3,
• with the proviso that the sum a+b+c is ≦4,
• aminoorganopolysiloxane (A) has at least one radical A per molecule, contains at least one aminoorgano group per molecule, and has a liquidity point or melting point between 20° C. and 60° C.

A polish comprising at least one aminoorganopolysiloxane which is solid at room temperature, contains fluoro groups, and is able to change its aggregate state reversibly as a result of changes in temperature, said at least one aminoorganopolysiloxane having the formula

• EhR3-hSiO(SiR2O)o(SiREO)mSiR3-hEh (IX),
• where
• h is 0, 1, or 2
• m and o independently are 0 or an integer from 1 to 1000,
• R is a monovalent, optionally substituted C1-40 hydrocarbon radical,
• E is a radical of the formula
• —R5—(NR6—CH2—CH2)d—NR62
• wherein
• R5 is a divalent, optionally substituted C1-12 hydrocarbon radical,
• R6 is hydrogen, methyl, ethyl, propyl, or butyl
• d is 0 or an integer from 1-8, wherein at least one R6 is H,
• and wherein said at least one aminoorganopolysiloxane contains at least one group E, and has a liquidity point or melting point between 20° C. and 60° C.