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US 6,333,445 B1Granted
Cryogenic separation process for the recovery of components from the products of a dehydrogenation reactor
AssigneeChart Inc.
InventorJohn V. O'Brien
Life of this patent
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Abstract
The olefin-hydrogen effluent vapor stream from a dehydrogenation process is separated by a cryogenic separation method utilizing a cryogenic separation system. The method does not require external refrigeration and reheats and portions an expander feed stream to extract energy and controls the warm end and cold end temperature differences in the primary heat exchanger to provide energy savings and economical operation and material use.
Claims25
A process for the separation of an olefinic hydrocarbon and hydrogen in a compressed effluent vapor stream from a dehydrogenation reactor, which process comprises:
- a) partially condensing the compressed effluent vapor stream in a first warm heat exchanger having a warm end and a cold end;
- b) separating the partially condensed compressed effluent vapor stream in a first primary separator to provide a first vapor product and a first liquid olefinic product;
- c) partially condensing the first vapor product in a second cold heat exchanger having a warm end and a cold end;
- d) separating the partially condensed first vapor product in a second separator to provide a second vapor product and a second liquid olefinic product;
- e) isentropically expanding, in a high pressure expander, the second vapor product to provide a third liquid olefin product and a third vapor product;
- f) reheating the third vapor product in the second cold heat exchanger;
- g) dividing the reheated third vapor product into a first portion and a second portion;
- h) reheating the first portion in the first warm heat exchanger and withdrawing a process vapor product comprising essentially hydrogen;
- i) expanding the second portion in a low pressure expander;
- j) reheating the expanded second portion in the second cold heat exchanger;
- k) subcooling a liquid paraffinic feed for use in the reactor in the first warm heat exchanger;
- l) combining the subcooled liquid paraffinic feed with the expanded reheated second portion to provide a combined stream;
- m) revaporizing the combined stream in the first warm heat exchanger;
- n) withdrawing the revaporized combined stream;
- o) combining the first, second, and third liquid olefinic products to provide a liquid combined stream;
- p) rewarming the liquid combined stream to an intermediate temperature between a warm end temperature and a cold end temperature in the first warm heat exchanger;
- q) flashing the rewarmed liquid combined stream in a liquid product drum to provide flashed vapor stream;
- r) pumping the flashed, rewarmed, liquid combined stream to a high pressure;
- s) reheating the pumped, high pressure, liquid combined stream in the first warm heat exchanger;
- and
- t) withdrawing the reheated, pumped, liquid combined stream from the first warm heat exchanger.
18 more elements
Dependencies are inferred from the claim text.