A method comprising forming a protective coating on a surface of a metallic part of a Ti-based alloy comprising titanium (Ti) and less than 9 wt % of aluminum (Al), by applying mechanical energy to particulates consisting essentially of at least one Si alloy selected from the group consisting of CrSi2, NbSi2, MoSi2, WSi2, ZrSi2 and HfSi2, in a direction toward said surface, wherein said protective coating contains at least a part of said particulates dispersed in a matrix of said Ti-based alloy, some of which dispersed particulates being connected to each other.