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US 6,297,209 B1Granted
Sequesterants as hypochlorite bleach enhancers
AssigneeThe Clorox Company
InventorsThomas W. Kaaret, William L. Smith
Life of this patent
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AssigneeThe Clorox Company
InventorsThomas W. Kaaret, William L. Smith
Estimating the term…
Sequestering agents for use as a whitening and fabric strength enhancer for aqueous hypochlorite bleach compositions are provided. It was found that the sequesterants when used with hypochlorite in the presence of soluble heavy metal ions, particularly iron and manganese ions, provide significantly improved whitening and fabric protection. Most preferably, the sequesterants are selected from polyacrylic acid, a polyacrylic acid derivative, a copolymer of acrylic acid or methacrylic acid and a comonomer which is maleic acid or maleic anhydride and mixtures thereof. In one aspect, the sequesterants are employed in a method for laundering fabrics comprising: a) providing, in a wash liquor containing (i) at least about 40 ppb of iron cations or (ii) at least about 10 ppb of manganese cations, or (iii) the cations of both (i) and (ii), and a fabric piece; and b) adding either prior to, contemporaneously with, or after, the step of providing of said fabric piece to said wash liquor a hypochlorite composition which comprises one or more of said sequesterants. Preferably the sequesterant comprises at least 0.1 ppm by weight of said wash liquor and the hypochlorite composition is an alkali metal hypochlorite and said sequesterant has a molecular weight of between about 500 and 500,000 daltons.
An aqueous hypochlorite bleach composition suitable for bleaching fabrics in wash liquors containing at least one of iron or manganese cations, said composition consisting essentially of an alkali metal hypochlorite and an effective amount of a non-crosslinked polyacrylic acid polymer or a copolymer of acrylic acid and maleic acid, said polymer or copolymer having a molecular weight of about 3,000 to about 70,000 daltons that mitigates the attack of said cations on said fabrics.
A method for laundering fabrics with improved whitening and reduced fabric damage, said method comprising:
A wash liquor containing (i) at least 40 ppb of iron cations or (ii) at least about 10 ppb of manganese cations, or (iii) the cations in both (i) and (ii), and said wash liquor further comprising:
Dependencies are inferred from the claim text.