Process for the manufacture of coarse aluminium hydroxide
AssigneeAlusuisse Technology & Management Ltd.
InventorsHans Jürg Schenk, Hans-Peter Breu, Arvind Bhasin
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AssigneeAlusuisse Technology & Management Ltd.
InventorsHans Jürg Schenk, Hans-Peter Breu, Arvind Bhasin
Estimating the term…
A process for the manufacture of coarse aluminum hydroxide via the Bayer Process. The process involves the decomposition of a supersaturated alkaline aluminate liquor in a two stage precipitation process having an agglomeration stage and a growth stage. The agglomeration stage takes place in agglomeration tanks, where the liquor is seeded with fine aluminum hydroxide to induce precipitation and formation of a suspension, followed by a growth stage, where the suspension is seeded with a coarse aluminium hydroxide. Typically, the feed of the supersaturated alkaline aluminate liquor is split over a first agglomeration tank at a higher liquor temperature of 70° to 100° C. and a second agglomeration tank or one or more of a series of second agglomeration tanks at a lower liquor temperature of 50° to 80° C.
A process for manufacturing coarse aluminium hydroxide by decomposition of a supersaturated alkaline aluminate liquor in a two stage precipitation process having an agglomeration stage in agglomeration tanks, connected in series, where the liquor is seeded with fine aluminium hydroxide to induce precipitation and formation of a suspension, the feed of the supersaturated alkaline aluminate liquor to the agglomeration stage is split into a first substream and said first substream is fed to a single first agglomeration tank or to the first and more of a series of first agglomeration tanks, at a higher liquor temperature of 70° to 100° C. and to a second substream and said second substream is fed to a second agglomeration tank or to a series of 2 or more second agglomeration tanks at a lower liquor temperature of 50° to 80° C., the residence time of the suspension in the agglomeration stage tanks is 3 to 12 hours, all of the supersaturated alkaline aluminate liquor being added during the agglomeration stage, followed by a growth stage, where the suspension is seeded with a coarse aluminium hydroxide, yielding at the end of precipitation a strong coarse product hydrate, giving after calcination a sandy alumina with low occluded soda content, compatible with a high liquor productivity.
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