Process for the production of grain oriented electrical steel strip having high magnetic characteristics, starting from thin slabs
AssigneeAcciai Speciali Terni S.p.A.
InventorsStefano Fortunati, Stefano Cicale', Giuseppe Abbruzzese
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Abstract
In the production of high permeability electrical steel, the control of condition of thin slab continuous casting allows to obtain advantageous solidification structures and precipitates. This, in turn, allows to decritize the process for controlling the grain dimensions and to add nitrogen to the cold rolled sheet, such as to immediately form aluminum nitride.
Claims11
Process for the production of high characteristics silicon steel strip, in which a steel containing in weight percent, 2.5-5 Si, 0.002-0.075 C, 0.05-0.4 Mn, <0.015% S or <0.015% (S+(0.503×Se)), 0.010-0.045 Al, 0.003-0.0130 N, up to 0.2 Sn, 0.040-0.03 Cu, remaining being iron and minor impurities, is continuously cast, high temperature annealed, hot rolled, cold rolled in a single step or in a plurality of steps with intermediate annealing, the cold rolled strip so obtained is annealed to perform primary annealing and decarburization, coated with annealing separator and box annealed to obtain final secondary recrystallization treatment, said process being characterized by the combination in cooperation relationship of:
- (i) continuously casting a thin slab having a thickness of between 20 and 80 mm utilizing
- a) a casting speed of 3 to 5 m/min,
- b) a steel temperature during the casting of between 20 and 40° C., higher than the liquids temperature of steel,
- c) such a cooling speed as to obtain a complete solidification within 30 to 100 s,
- d) a mold oscillation amplitude of between 1 and 10 mm, and e) an oscillation frequency of between 200 and 400 cycles per minute;
- (ii) equalizing the thus obtained slabs at a temperature comprised between 1150 and 1300° C.;
- (iii) hot rolling the equalized slabs with a starting rolling temperature of between 1000 and 1200° C. and a finishing rolling temperature of between 850 and 1050° C.;
- (iv) continuously annealing the hot rolled strips for 30 to 300 s at a temperature no less than 850° C. and maintaining said temperature for 30 to 300 s, and then cooling them;
- (v) cold rolling the strip in a single step or in a plurality of steps with intermediate annealing, the last step being performed with a reduction ratio of at least 80%;
- (vi) continuously treating the cold rolled strip to obtain primary annealing and decarburization for a total time of 100 to 350s, at a temperature comprised between 850 and 1050° C. in a wet nitrogen/hydrogen atmosphere, with a ratio between partial pressures of water vapor and hydrogen according (pH2O/pH2) comprised between 0.3 and 0.7;
- (vii) coating the strip with annealing separator, coiling it and box annealing the coils in an atmosphere having the following compositions during the heating-up:
- hydrogen mixed with at least 30% vol nitrogen up to 900° C., hydrogen mixed with at least 40% vol nitrogen up to 1100-1200°, then, maintaining the coils at this temperature in pure hydrogen.
Dependencies are inferred from the claim text.