Method for continuous production of dihydroxydiphenylalkanes

A continuous process for the production of dihydroxydiarylalkane comprising

• (i) reacting an aromatic hydroxy compound with at least some ketone and at least some isoalkenylphenol at the lowest possible temperature in a first of a cascade of at least two reactors to form a reaction mixture and continuing the reaction at increasing temperature in the succeeding at least one reactor into which ketone and isoalkenylphenol are apportioned, and removing acidic constituents from the reaction mixture, and
• (ii) distilling water of reaction and residual ketone from the reaction mixture to form a dry reaction mixture, and
• (iii) distilling phenol from said dry reaction mixture to obtain a first bottom product, and
• (iv) distilling said first bottom product to obtain a distillate rich in dihydroxydiarylalkane and a second bottom product containing high-boiling fractions, and
• (v) distilling said distillate to obtain a second distillate containing fractions which are lower-boiling than dihydroxydiarylalkane and to obtain a third bottom product containing bisphenol,
• (vi) combining said second bottom product with said second distillate to form a combination and continuously cracking said combination in the presence of a base, in a multi-step reactive distillation, to produce (a) phenol and isoalkenylphenol which pass overhead and (b) a high-boiling bottom product,
• (vii) acidifying and cracking said high-boiling bottom product in reactive distillation, to produce phenol and resin, and
• (viii) recycling the phenol distillate obtained in (vii) and the phenol and isoalkenylphenol produced in (vi), optionally after purification, to said reaction mixture said aromatic hydroxy compounds being unsubstituted in the p-position and containing no second order substituents.