Yttria-stabilized zirconia feed material
AssigneeGeneral Electric Company
InventorRobert W. Bruce
Life of this patent
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Abstract
A method is provided for physical vapor deposition of ceramic thermal barrier coatings and articles made therefrom Impurity levels in conventional yttria stabilized zirconia source materials have caused undesired spitting (eruptions) due to a combined effect of various impurities thereby requiring relatively low evaporation rates to control the level of spitting during the process. The present method provides a high purity source material having a purity index sufficiently low to result in reduced spitting in the vapor deposition process and to permit in evaporation rates. Reducing the density of the source material has also been found to reduce spitting. The method permits higher processing rates and/or reduced levels of spitting.
Claims19
A solid feed material of yttria stabilized zirconia having an impurity index of less than 7000, said impurity index being determined by the formula
- impurity index=8×Ca+7×C+7×Fe+7×Si+7×Ti+7×S+5×Mg+5×Na+4×Bi+3×Al+2×P+2×Ta
- wherein elemental values are in parts per million by weight based on the total weight of feed material.
A solid feed material of yttria stabilized zirconia having an impurity index of less than 5000, said impurity index being determined by the formula
- impurity index=8×Ca+7×C+7×Fe+7×Si+7×Ti+7×S+5×Mg+5×Na+4×Bi+3×Al+2×P+2×Ta
- wherein elemental values are in parts per million by weight based on the total weight of feed material, and wherein the feed material has a density of less than 3.6 g/cc.
Dependencies are inferred from the claim text.