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US 6,187,506 B1Granted
Antireflective coating for photoresist compositions
AssigneeClariant Finance (BVI) Limited
InventorsShuji Ding, Dinesh N. Khanna, Mark A. Spak, Dana L. Durham, Jianhui Shan, Eleazer Gonzalez
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Abstract
The present invention relates to a novel antireflective coating solution and a process for its use in photolithography. The antireflective coating solution comprises a novel polymer and an organic solvent or mixture of solvents, where the novel polymer comprises a unit containing a dye that absorbs from about 180 nm to about 450 nm and does not contain a crosslinking group.
Claims28
A coating composition for use in photolithography, comprising
- a) a polymer having a structure,
- where,
- R1-R3 are independently H, (C1-C10) alkyl or (C1-C10) alkoxy,
- R5-R8 do not have a crosslinking group and are independently H, (C1-C10) alkyl, (C1-C10) alkoxy, hydroxyalkyl, nitro, halide, cyano, aryl, alkylaryl, alkenyl, dicyanovinyl, SO2CF3, COOZ, SO3Z, COZ, OZ, NZ2, SZ, SO2Z, NHCOZ, SO2NZ2, where Z is H or (C1-C10) alkyl, hydroxy (C1-C10) alkyl, (C1-C10)alkylOCOCH2COCH3, or R7 and R8 combine to form a cyclic group,
- X1 is C═O, OCO, CONH, O, aryl, (C1-C10) alkyl, cyclohexyl, pyridine or pyrollidone,
- X2 is S, S(C1-C10) alkyl, O, O(C1-C10) alkyl, NH, N(C1-C10) alkyl, alkyl, or hydroxyalkyl(C1-C10),
- n is independently 0-2,
- A is an electronwithdrawing group,
- Y is a conjugated moiety e.g. N═N, CW═CW, CW═N, or N═CW, where W is H, (C1-C10) alkyl or (C1-C10) alkoxy,
- x>0, and y≧0, and
- B is selected from a 5-10 membered aromatic group, polyaromatic group or a heterocyclic aromatic group;
- and,
- b) a suitable solvent.
10 more elements
Dependencies are inferred from the claim text.